화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.21, 1127-1131, January, 2015
DOI10.1016/j.jiec.2014.05.024  Export Citation
Silver-exchanged heteropolyacid catalyst (Ag1H2PW): An efficient heterogeneous catalyst for the synthesis of 5-ethoxymethylfurfural from 5-hydroxymethylfurfural and fructose
Yongshen Ren, Bing Liu†, Zehui Zhang, and Jintao Lin1, †
  • Key Laboratory of Catalysis and Material Sciences of the State Ethnic Affairs Commission&Ministry of Education, College of Chemistry and Material Sciences, South-Central University for Nationalities, Wuhan 430074, China
  • 1Department of Biotechnology, Dalian Medical University, Dalian 116044, China
E-mail:,
Three kinds of silver-exchanged phosphotungstic acid catalysts were prepared and used for the synthesis of potential biofuel 5-ethoxymethylfurfural (EMF). It was found that the partially silver exchanged phosphotungstic acid (Ag1H2PW) showed the best catalytic activity among silver exchanged phosphotungstic acids prepared. The highest EMF yield of 88.7% was obtained from 5-hydroxymethylfurfural (HMF) at 100 ℃ after 10 h. Furthermore, Ag1H2PW also showed high catalytic activity for the one-pot conversion of fructose into EMF with a yield of 69.5%. In addition, Ag1H2PW could be reused several times without a significant loss of its catalytic activity.
Keywords:5-Ethoxymethylfurfural;5-Hydroxymethylfurfural;Fructose;Silver;Phosphotungstic acid
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