화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.31, 199-215, November, 2015
DOI10.1016/j.jiec.2015.06.024  Export Citation
Batch adsorptive removal of benzoic acid from aqueous solution onto modified natural vermiculite: Kinetic, isotherm and thermodynamic studies
Ehsan Sadeghi Pouya1, Hossein Abolghasemi1, 2, †, Mohamad Esmaieli1, 3, Hooman Fatoorehchi1, 3, Seyed Jalaledin Hashemi1, 4, and Alireza Salehpour5
  • 1Center for Separation Processes Modeling and Nano-Computations, School of Chemical Engineering, College of Engineering, University of Tehran, P.O. Box 11365-4563, Tehran, Iran
  • 2Oil and Gas Center of Excellence, University of Tehran, Tehran, Iran
  • 3, Iran
  • 4Pulp and Paper Research Center, Department of Chemical Engineering, McGill University, Montreal, Canada
  • 5Laboratory for Instrumental Analysis, School of Chemical Engineering, College of Engineering, University of Tehran, Tehran, Iran
E-mail:
The performance of modified vermiculite for the batch adsorption of benzoic acid from aqueous solution was studied. Grinding treatment enhanced the ion exchange ability of natural vermiculite. Cetyltrimethylammonium bromide improved the adsorptive characteristics of ground vermiculite better than cetylpyridinium bromide. The optimum conditions were obtained as the adsorbent dosage of 0.5 g/50 mL, initial pH of 3.5 and contact time of about 140 min. The pseudo-second-order model provided a good correlation of the kinetic data. The equilibrium data were well described by the Langmuir and Temkin equations. Thermodynamically, it was concluded that the process is endothermic and spontaneous.
Keywords:Adsorption;Benzoic acid;Vermiculite;Grinding treatment;Surfactant modification;Cetyltrimethylammonium bromide
  1. Ayranci E, Hoda N, Bayram E, J. Colloid Interface Sci., 284(1), 83 (2005)
  2. Wibbertmann A, Kielhorn J, Koennecker G, Mangelsdorf I, Melber C, Concise International Chemical Assessment Document 26: Benzoic Acid and Sodium Benzoate, Published under the joint sponsorship of the United Nations Environment Programme, the International Labour Organization and the World Health Organization, Geneva, 2005.
  3. Huang JH, Wang G, Huang KL, Chem. Eng. J., 168(2), 715 (2011)
  4. Gandhi VG, Mishra MK, Rao MS, Kumar A, Joshi PA, Shah DO, J. Ind. Eng. Chem., 17(2), 331 (2011)
  5. Velegraki T, Balayiannis G, Diamadopoulos E, Katsaounis A, Mantzavinos D, Chem. Eng. J., 160(2), 538 (2010)
  6. Zachritz WH, Lundie LL, Wang H, Ecol. Eng., 7, 105 (1996)
  7. Bayram E, Ayranci E, Sep. Purif. Technol., 86, 113 (2012)
  8. Xin XD, Si W, Yao ZX, Feng R, Du B, Yan LG, Wei Q, J. Colloid Interface Sci., 359(2), 499 (2011)
  9. Yıldız N, Gonulsen R, Koyuncu H, Calımlı A, Colloids Surf. A: Physicochem. Eng. Asp., 260, 87 (2005)
  10. Meier DM, Urakawa A, Baiker A, Phys. Chem. Chem. Phys., 11, 10132 (2009)
  11. Yan L, Wang J, Yu H, Wei Q, Du B, Shan X, Appl. Clay Sci., 37, 226 (2007)
  12. Chai KG, Ji HB, Chem. Eng. J., 203, 309 (2012)
  13. Soto ML, Moure A, Dominguez H, Parajo JC, J. Food Eng., 105(1), 1 (2011)
  14. Hamed MM, Ahmed IM, Metwally SS, J. Ind. Eng. Chem., 20(4), 2370 (2014)
  15. Jin X, Jiang M, Duc J, Chen Z, J. Ind. Eng. Chem., 20(5), 3025 (2014)
  16. Raman KVV, Jackson ML, Clay Clay Min., 12, 423 (1963)
  17. Xie Y, Wang A, J. Compos. Mater., 43, 1 (2009)
  18. Drelich J, Li BW, Bowen P, Hwang JY, Mills O, Hoffman D, Appl. Surf. Sci., 257(22), 9435 (2011)
  19. Pe´ rez-Rodrı´guez JL, Carrera F, Poyato J, Pe´rez-Maqueda LA, Nanotechnology, 13, 382 (2002)
  20. Zhao MF, Tang ZB, Liu P, J. Hazard. Mater., 158(1), 43 (2008)
  21. Tang J, Yang ZF, Yi YJ, Procedia Environ. Sci., 13, 2179 (2012)
  22. Medeiros MA, Sansiviero MTC, Araujo MH, Lago RM, Appl. Clay Sci., 45, 213 (2009)
  23. Mysore D, Viraraghavan T, Jin Y, Water Res., 39, 2643 (2005)
  24. Yu XB, Wei CH, Ke L, Hu Y, Xie XQ, Wu HZ, J. Hazard. Mater., 180(1-3), 499 (2010)
  25. Nezamzadeh-Ejhieh A, Shahanshahi M, J. Ind. Eng. Chem., 19(6), 2026 (2013)
  26. Lin JW, Zhan YH, Zhu ZL, Xing YQ, J. Hazard. Mater., 193, 102 (2011)
  27. Guan HD, Bestland E, Zhu CY, Zhu HL, Albertsdottir D, Hutson J, Simmons CT, Ginic-Markovic M, Tao XA, Ellis AV, J. Hazard. Mater., 183(1-3), 616 (2010)
  28. Rosales-Landeros C, Barrera-Dı´az CE, Bilyeu B, Guerrero VV, Nunez FU, Am. J. Anal. Chem., 4, 8 (2013)
  29. Simpson JA, Bowman RS, J. Contam. Hydrol., 108, 1 (2009)
  30. Maqueda C, Perez-Rodriguez JL, Subrt J, Murafa N, Appl. Clay Sci., 44, 178 (2009)
  31. Hongo T, Yoshino S, Yamazaki A, Yamasaki A, Satokawa S, Appl. Clay Sci., 70, 74 (2012)
  32. Bartels JM, Sparks DL, Methods of Soil Analysis: Part 3, Chemical Methods, Soil Science Society of America, Madison, 2009.
  33. Filipovic-Petrovic L, Kostic-Gvozdenovic L, Eric-Antonic S, J. Serb. Chem. Soc., 67, 753 (2002)
  34. Gladysz-Plaska A, Majdan M, Pikus S, Sternik D, Chem. Eng. J., 179, 140 (2012)
  35. Proverbio ZE, Bardavid SM, Arancibia EL, Schulz PC, Colloids Surf. A: Physicochem. Eng. Asp., 214, 167 (2003)
  36. Ho OB, J. Colloid Interface Sci., 198(2), 249 (1998)
  37. Teixeira APC, Purceno AD, Barros AS, Lemos BRS, Ardisson JD, Macedo WAA, Nassor ECO, Amorim CC, Moura FCC, Hernandez-Terrones MG, Portela FM, Lago RM, Catal. Today, 190(1), 133 (2012)
  38. Mikutta R, Mikutta C, Kalbitz K, Scheel T, Kaiser K, Jahn R, Geochim. Cosmochim. Acta, 71, 2569 (2007)
  39. Yasuda M, Ikeda K, Esumi K, Meguro K, Langmuir, 6, 949 (1990)
  40. Zhu J, Zhu L, Zhu R, Chen B, Clay Clay Min., 56, 144 (2008)
  41. Joule JA, Mills K, Heterocyclic Chemistry, 5th ed., John Wiley & Sons, Chichester, 2010.
  42. Lin J, Zhan Y, Zhu Z, Colloids Surf. A: Physicochem. Eng. Asp., 384, 9 (2011)
  43. Katal R, Baei MS, Rahmati HT, Esfandian H, J. Ind. Eng. Chem., 18(1), 295 (2012)
  44. Shakir K, Ghoneimy HF, Elkafrawy AF, Beheir SG, Refaat M, J. Hazard. Mater., 150, 765 (2008)
  45. Babic BM, Milonjic SK, Polovina MJ, Kaludierovic BV, Carbon, 37, 477 (1999)
  46. Ghaedi M, Ghaedi AM, Abdi F, Roosta M, Sahraei R, Daneshfar A, J. Ind. Eng. Chem., 20(3), 787 (2014)
  47. Gritzapis PC, Efstathiou CE, Hadjiioannou TP, Anal. Chim. Acta, 171, 165 (1985)
  48. Anirudhan TS, Ramachandran M, J. Colloid Interface Sci., 299(1), 116 (2006)
  49. Anirudhan TS, Ramachandran M, Appl. Clay Sci., 35, 276 (2007)
  50. Huang JH, Liu YF, Wang XG, J. Hazard. Mater., 160(2-3), 382 (2008)
  51. Babaeivelni K, Khodadoust AP, J. Colloid Interface Sci., 394, 419 (2013)
  52. Chen GQ, Zhang WJ, Zeng GM, Huang JH, Wang LA, Shen GL, J. Hazard. Mater., 186(2-3), 2138 (2011)
  53. Deng H, Yu XL, Chem. Eng. J., 184, 205 (2012)
  54. Yousef RI, El-Eswed B, Al-Muhtaseb AH, Chem. Eng. J., 171(3), 1143 (2011)
  55. Mall ID, Srivastava VC, Argawal NK, Dyes Pigment., 69, 210 (2006)
  56. Tan IAW, Ahmad AL, Hameed BH, J. Hazard. Mater., 154(1-3), 337 (2008)
  57. Caliskan N, Kul AR, Alkan S, Sogut EG, Alacabey I, J. Hazard. Mater., 193, 27 (2011)
  58. Alberti G, Amendola V, Pesavento M, Biesuz R, Coord. Chem. Rev., 256, 28 (2012)
  59. Lagergren S, Sven K, Vetenskapsakad. Handl., 24, 1 (1898)
  60. Ho YS, McKay G, Process Biochem., 34(5), 451 (1999)
  61. Sun CM, Zhang GH, Wang CH, Qu RJ, Zhang Y, Gu QY, Chem. Eng. J., 172(2-3), 713 (2011)
  62. Huang L, Zhou Y, Guo X, Chen Z, J. Ind. Eng. Chem., http://dx.doi.org/10.1016/j.jiec.2014.07.021. (2014)
  63. Foo KY, Hameed BH, Chem. Eng. J., 156(1), 2 (2010)
  64. Nasuha N, Hameed BH, Din ATM, J. Hazard. Mater., 175(1-3), 126 (2010)
  65. Hameed BH, J. Hazard. Mater., 161(2-3), 753 (2009)
  66. Ocampo-Perez R, Leyva-Ramos R, Mendoza-Barron J, Guerrero-Coronado RM, J. Colloid Interface Sci., 364(1), 195 (2011)
  67. Weber WJ, Morris JC, J. Sanit. Eng. Div. Am. Soc. Civil Eng., 89, 31 (1963)
  68. Cheung WH, Szeto YS, McKay G, Bioresour. Technol., 98(15), 2897 (2007)
  69. McKay G, Blair HS, J. Appl. Polym. Sci., 28, 1767 (1983)
  70. Bhattacharyya KG, Sharma A, Dyes Pigment., 65, 51 (2005)
  71. Foroughi-dahr M, Abolghasemi H, Esmaieli M, Nazari G, Rasem B, Process Saf. Environ. Protect., 95, 226 (2015)
  72. Hamdaoui O, Naffrechoux E, J. Hazard. Mater., 147(1-2), 381 (2007)
  73. Mendez-Diaz JD, Daiem MMA, Rivera-Utrilla J, Sanchez-Polo M, Bautista-Toledo I, J. Colloid Interface Sci., 369, 358 (2012)
  74. Chai KG, Ji HB, Chem. Eng. J., 203, 309 (2012)
  75. Wang JN, Li AM, Xu L, Zhou Y, J. Hazard. Mater., 169(1-3), 794 (2009)
  76. Otero M, Zabkova M, Rodriques M, Sep. Purif. Technol., 45, 56 (2005)
  77. Rakic V, Rajic N, Dakovic A, Auroux A, Microporous Mesoporous Mater., 166, 185 (2013)
  78. Foroughi-dahr M, Abolghasemi H, Esmaili MM, Shojamoradi A, Fatoorehchi H, Chem. Eng. Commun., 202, 181 (2014)
  79. Huang JH, Liu YF, Wang XG, J. Hazard. Mater., 160(2-3), 382 (2008)
  80. Anirudhan TS, Suchithra PS, J. Ind. Eng. Chem., 16(1), 130 (2010)
  81. Katal R, Sefti MV, Jafari M, Dehaghani AHS, Sharifian S, Ghayyem MA, J. Ind. Eng. Chem., 18(1), 230 (2012)
  82. De Haro MCJ, Blanes JMM, Poyato J, Pe´rez-Maqueda LA, Lerf A, Pe´ rez-Rodriguez JL, J. Phys. Chem. Solids, 65, 435 (2004)
  83. Maqueda C, Romero AS, Morillo E, Pe´ rez-Rodriguez JL, J. Phys. Chem. Solids, 68, 1220 (2007)
  84. Su J, Lin HF, Wang QP, Xie ZM, Chen ZL, Desalination, 269(1-3), 163 (2011)
  85. Socrates G, Infrared and Raman Characteristic Group Frequencies: Tables and Charts, 3rd ed., John Wiley & Sons, Chichester, 2001.
  86. Slade PG, Raupach M, Emerson WW, Clay Clay Min., 26, 125 (1978)
  87. Terfkhi MC, Taleb F, Gossart P, Semmoud A, Addou A, J. Photochem. Photobiol. A-Chem., 198, 205 (2008)
  88. Matusinovic Z, Rogosic M, Sipusic J, Macan J, Polym. Eng. Sci., 48(10), 2027 (2008)