화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.43, 133-141, November, 2016
DOI10.1016/j.jiec.2016.07.059  Export Citation
Catalytic transfer hydrogenation of ethyl levulinate into g-valerolactone over mesoporous Zr/B mixed oxides
Jian He1, Hu Li1, Yanxiu Liu1, Wenfeng Zhao1, Tingting Yang1, Wei Xue1, and Song Yang1, 2, †
  • 1Center for Research and Development of Fine Chemicals, State-Local Joint Engineering Laboratory for Comprehensive Utilization of Biomass, State Key Laboratory Breeding Base of Green Pesticide and Agricultural Bioengineering (Ministry of Education), Guizhou University, Guiyang 550025, China
  • 2School of Pharmacy, East China University of Science & Technology, Shanghai 200237, China
E-mail:
A series of mesoporous acid.base bifunctional Zr/B mixed oxides with different molar ratios were prepared by a sol-gel method, and developed for conversion of ethyl levulinate (EL) to g-valerolactone (GVL) by using alcohol as hydrogen source. The morphological structures and physico-chemical characteristics of the synthesized materials were identified by various techniques. A high GVL yield of 88.5% was achieved from EL in 2-propanol when Zr1B1 was used. And acid-base sites played a synergic role in synthesizing GVL from EL as evident by poisoning experiments. Furthermore, the catalyst could be reused several times without significant loss of its catalytic activity.
Keywords:γ-Valerolactone;Biomass;Heterogeneous catalysis;Mesoporous material;Catalytic transfer hydrogenation
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