화학공학소재연구정보센터
Macromolecular Research, Vol.25, No.8, 856-863, August, 2017
Preparation of Silver-Coated Silk Fabrics with Antibacterial Activity Using Silver Carbamate and Hydrogen Reduction
E-mail:
A new method was studied to efficiently metallize silk fabrics, and silvercoated silk fabrics were prepared and characterized. In this study, silver 2-ethylhexylcarbamate was used as the silver precursor, and a hydrogen atmosphere was used to reduce the precursors, thus forming silver nanoparticles on the surface of silk fabric. The silver-coated silk fabric was characterized by scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), and Fourier-transform infrared (FT-IR) spectroscopy, and the results confirmed that 20-70 nm silver nanoparticles were uniformly generated without damaging the silk fabric. The silver-coated silk fabric showed excellent ultraviolet blocking properties and antibacterial activity against Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus). This method provides a way to improve the antibacterial ability of silk fabrics while avoiding damage to the silk.
  1. He X, Zhang M, Yin L, Wang Y, Fan H, Yang S, Zhao X, Song M, Mater. Rev., 7, 013 (2009)
  2. Borkow G, Gabbay J, Curr. Chem. Biol., 3, 272 (2009)
  3. Wang S, Hou W, Wei L, Jia H, Liu X, Xu B, Surf. Coat. Technol., 202, 460 (2007)
  4. Gao Y, Cranston R, Text. Res. J., 78, 60 (2008)
  5. Montazer M, Afjeh MG, J. Appl. Polym. Sci., 103(1), 178 (2007)
  6. Altman GH, Diaz F, Jakuba C, Calabro T, Horan RL, Chen JS, Lu H, Richmond J, Kaplan DL, Biomaterials, 24, 401 (2003)
  7. Burrell RE, Ostomy Wound Manage., 49, 19 (2003)
  8. Le Ouay B, Stellacci F, Nano Today, 10(3), 339 (2015)
  9. Lara HH, Garza-Trevino EN, Ixtepan-Turrent L, Singh DK, J. Nanobiotechnol., 9, 30 (2011)
  10. Rai M, Yadav A, Gade A, Biotechnol. Adv., 27, 76 (2009)
  11. Rai MK, Deshmukh SD, Ingle AP, Gade AK, J. Appl. Microbiol., 112(5), 841 (2012)
  12. Jeong L, Cho D, Kwon OH, Min BM, Park WH, Macromol. Res., 22(7), 796 (2014)
  13. Panthi G, Park M, Park SJ, Kim HY, Macromol. Res., 23(2), 149 (2015)
  14. Kang SW, Hong J, Kim JH, Kang YS, Macromol. Res., 19(4), 413 (2011)
  15. Aymonier C, Schlotterbeck U, Antonietti L, Zacharias P, Thomann R, Tiller JC, Mecking S, Chem. Commun., 24, 3018 (2002)
  16. Shi XL, Wang S, Duan XL, Zhang QX, Mater. Chem. Phys., 112(3), 1110 (2008)
  17. Chou KS, Lu YC, Lee HH, Mater. Chem. Phys., 94(2-3), 429 (2005)
  18. Shchukin DG, Radtchenko IL, Sukhorukov GB, Chem. Phys. Chem., 4, 1101 (2003)
  19. Shin HS, Yang HJ, Kim SB, Lee MS, J. Colloid Interface Sci., 274(1), 89 (2004)
  20. Khanna P, Subbarao V, Mater. Lett., 57, 2242 (2003)
  21. Rogers JV, Parkinson CV, Choi YW, Speshock JL, Hussain SM, Nanoscale Res. Lett., 3, 129 (2008)
  22. Anuradha K, Bangal P, Madhavendra SS, Macromol. Res., 24(2), 152 (2016)
  23. Kim KA, Cha JR, Gong MS, Bull. Korean Chem. Soc., 34, 505 (2013)
  24. Shin US, Hong HK, Kim HW, Gong MS, Bull. Korean Chem. Soc., 32, 1583 (2011)
  25. Kim KY, Gong MS, Park CK, Bull. Korean Chem. Soc., 33, 3987 (2012)
  26. Park HS, Park HS, Gong MS, Macromol. Res., 18(9), 897 (2010)
  27. Hong HK, Gong MS, Park CK, Bull. Korean Chem. Soc., 30, 2669 (2009)
  28. Alessio R, Dell’Amico DB, Calderazzo F, Englert U, Guarini A, Labella L, Strasser P, Helv. Chim. Acta, 81, 219 (1998)
  29. Alimohammadi F, Gashti MP, Shamei A, Kiumarsi A, Superlattices Microstruct., 52, 50 (2012)
  30. Emam HE, Bechtold T, Appl. Surf. Sci., 357, 1878 (2015)
  31. Reinert G, Fuso F, Hilfiker R, Schmidt E, AATCC Rev., 29, 31 (1997)
  32. Shivananda CS, Rao BL, Pasha A, Sangappa Y, IOP Conference Series: Mater. Sci. Eng., 149, 012175 (2016).
  33. Lu Q, Hu X, Wang X, Kluge JA, Lu S, Cebe P, Kaplan DL, Acta Biomater., 6, 1380 (2010)
  34. Teimouri A, Ebrahimi R, Emadi R, Beni BH, Chermahini AN, Int. J. Biol. Macromol., 76, 292 (2015)
  35. Dhas SP, John SP, Mukherjee A, Chandrasekaran N, Biotechnol. Appl. Biochem., 61, 322 (2014)
  36. Zhang G, Liu Y, Gao X, Chen Y, Nanoscale Res. Lett., 9, 216 (2014)
  37. Boulet-Audet M, Vollrath F, Holland C, J. Exp. Biol., 218, 3138 (2015)
  38. Zhang F, Wu X, Chen Y, Lin H, Fibers Polym., 10, 496 (2009)
  39. Murray RGE, Steed P, Elson HE, Can. J. Microbiol., 11, 547 (1965)