Macromolecular Research, Vol.25, No.8, 856-863, August, 2017
Preparation of Silver-Coated Silk Fabrics with Antibacterial Activity Using Silver Carbamate and Hydrogen Reduction
E-mail:
A new method was studied to efficiently metallize silk fabrics, and silvercoated silk fabrics were prepared and characterized. In this study, silver 2-ethylhexylcarbamate was used as the silver precursor, and a hydrogen atmosphere was used to reduce the precursors, thus forming silver nanoparticles on the surface of silk fabric. The silver-coated silk fabric was characterized by scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), and Fourier-transform infrared (FT-IR) spectroscopy, and the results confirmed that 20-70 nm silver nanoparticles were uniformly generated without damaging the silk fabric. The silver-coated silk fabric showed excellent ultraviolet blocking properties and antibacterial activity against Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus). This method provides a way to improve the antibacterial ability of silk fabrics while avoiding damage to the silk.
- He X, Zhang M, Yin L, Wang Y, Fan H, Yang S, Zhao X, Song M, Mater. Rev., 7, 013 (2009)
- Borkow G, Gabbay J, Curr. Chem. Biol., 3, 272 (2009)
- Wang S, Hou W, Wei L, Jia H, Liu X, Xu B, Surf. Coat. Technol., 202, 460 (2007)
- Gao Y, Cranston R, Text. Res. J., 78, 60 (2008)
- Montazer M, Afjeh MG, J. Appl. Polym. Sci., 103(1), 178 (2007)
- Altman GH, Diaz F, Jakuba C, Calabro T, Horan RL, Chen JS, Lu H, Richmond J, Kaplan DL, Biomaterials, 24, 401 (2003)
- Burrell RE, Ostomy Wound Manage., 49, 19 (2003)
- Le Ouay B, Stellacci F, Nano Today, 10(3), 339 (2015)
- Lara HH, Garza-Trevino EN, Ixtepan-Turrent L, Singh DK, J. Nanobiotechnol., 9, 30 (2011)
- Rai M, Yadav A, Gade A, Biotechnol. Adv., 27, 76 (2009)
- Rai MK, Deshmukh SD, Ingle AP, Gade AK, J. Appl. Microbiol., 112(5), 841 (2012)
- Jeong L, Cho D, Kwon OH, Min BM, Park WH, Macromol. Res., 22(7), 796 (2014)
- Panthi G, Park M, Park SJ, Kim HY, Macromol. Res., 23(2), 149 (2015)
- Kang SW, Hong J, Kim JH, Kang YS, Macromol. Res., 19(4), 413 (2011)
- Aymonier C, Schlotterbeck U, Antonietti L, Zacharias P, Thomann R, Tiller JC, Mecking S, Chem. Commun., 24, 3018 (2002)
- Shi XL, Wang S, Duan XL, Zhang QX, Mater. Chem. Phys., 112(3), 1110 (2008)
- Chou KS, Lu YC, Lee HH, Mater. Chem. Phys., 94(2-3), 429 (2005)
- Shchukin DG, Radtchenko IL, Sukhorukov GB, Chem. Phys. Chem., 4, 1101 (2003)
- Shin HS, Yang HJ, Kim SB, Lee MS, J. Colloid Interface Sci., 274(1), 89 (2004)
- Khanna P, Subbarao V, Mater. Lett., 57, 2242 (2003)
- Rogers JV, Parkinson CV, Choi YW, Speshock JL, Hussain SM, Nanoscale Res. Lett., 3, 129 (2008)
- Anuradha K, Bangal P, Madhavendra SS, Macromol. Res., 24(2), 152 (2016)
- Kim KA, Cha JR, Gong MS, Bull. Korean Chem. Soc., 34, 505 (2013)
- Shin US, Hong HK, Kim HW, Gong MS, Bull. Korean Chem. Soc., 32, 1583 (2011)
- Kim KY, Gong MS, Park CK, Bull. Korean Chem. Soc., 33, 3987 (2012)
- Park HS, Park HS, Gong MS, Macromol. Res., 18(9), 897 (2010)
- Hong HK, Gong MS, Park CK, Bull. Korean Chem. Soc., 30, 2669 (2009)
- Alessio R, Dell’Amico DB, Calderazzo F, Englert U, Guarini A, Labella L, Strasser P, Helv. Chim. Acta, 81, 219 (1998)
- Alimohammadi F, Gashti MP, Shamei A, Kiumarsi A, Superlattices Microstruct., 52, 50 (2012)
- Emam HE, Bechtold T, Appl. Surf. Sci., 357, 1878 (2015)
- Reinert G, Fuso F, Hilfiker R, Schmidt E, AATCC Rev., 29, 31 (1997)
- Shivananda CS, Rao BL, Pasha A, Sangappa Y, IOP Conference Series: Mater. Sci. Eng., 149, 012175 (2016).
- Lu Q, Hu X, Wang X, Kluge JA, Lu S, Cebe P, Kaplan DL, Acta Biomater., 6, 1380 (2010)
- Teimouri A, Ebrahimi R, Emadi R, Beni BH, Chermahini AN, Int. J. Biol. Macromol., 76, 292 (2015)
- Dhas SP, John SP, Mukherjee A, Chandrasekaran N, Biotechnol. Appl. Biochem., 61, 322 (2014)
- Zhang G, Liu Y, Gao X, Chen Y, Nanoscale Res. Lett., 9, 216 (2014)
- Boulet-Audet M, Vollrath F, Holland C, J. Exp. Biol., 218, 3138 (2015)
- Zhang F, Wu X, Chen Y, Lin H, Fibers Polym., 10, 496 (2009)
- Murray RGE, Steed P, Elson HE, Can. J. Microbiol., 11, 547 (1965)