화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.56, 234-247, December, 2017
DOI10.1016/j.jiec.2017.07.016  Export Citation
Corrosion inhibition properties of two imidazolium ionic liquids with hydrophilic tetrafluoroborate and hydrophobic hexafluorophosphate anions in acid medium
Yangyang Guo, Bin Xu1, Ying Liu†, Wenzhong Yang†, Xiaoshuang Yin, Yun Chen, Jinxun Le, and Zhihao Chen
  • College of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 210009, China
  • 1Nanjing Institute of Environmental Sciences, Ministry of Environmental Protection, Nanjing 210042, China
E-mail:,
The ionic liquids, 1-vinyl-3-aminopropylimidazolium hexafluorophosphate ([VAIM][PF6]) and 1-vinyl-3- aminopropylimidazolium tetrafluoroborate ([VAIM][BF4]) acted as the corrosion inhibitors. Weight loss measurements showed the corrosion inhibition efficiencies of [VAIM][PF6] and [VAIM][BF4] were 90.53% and 54.01% at 45 °C, respectively. The ILs were mix-type inhibitors. Raising the temperature can have a decreased inhibition efficiency of [VAIM][BF4], while [VAIM][PF6] presented an opposite trend. In addition, [VAIM][PF6] obeyed Langmuir monolayer adsorption isotherm, while [VAIM][BF4] obeyed EIAwady kinetic-thermodynamic adsorption for blocking active sites. Moreover, Molecular Dynamic Simulations showed that [VAIM][PF6] owned a higher adsorption energy, which may be responsible for the more adsorption groups of [VAIM][PF6].
Keywords:Ionic liquid;Corrosion inhibition;Acid solution;Polarization EIS
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