Novel estimation method of operating life in lithium-ion pouch cells

Hyosung Kim; Jaekwang Kim; Nayeong Kim; Ilbok Lee; Keebum Hwang; Joongho Bae; Songhun Yoon

Journal of Industrial and Engineering Chemistry, Vol.67, 266-275, November, 2018

DOI10.1016/j.jiec.2018.06.037 Export Citation

Novel estimation method of operating life in lithium-ion pouch cells

Hyosung Kim, Jaekwang Kim, Nayeong Kim, Ilbok Lee, Keebum Hwang, Joongho Bae, and Songhun Yoon^†

School of Integrative Engineering, Chung-Ang University, 221, Heukseok-Dong, Dongjak-Gu, Seoul 156-756, Republic of Korea

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Herein, a novel operating life (OL) test method was evaluated with 200 mAh pouch-type lithium ion batteries. By combining the calendar life (CL) test with intermediate pulse power cycling, more realistic life prediction was possible, which encompassed real operation of batteries accompanying with thermal acceleration. Larger capacity decrease and resistance increase of pouch cell were observed in the OL test, which was well explained using the SEI film growth model. After dissemble of pouch cell, capacity loss and resistance increase mostly occurred within anode, reflecting that SEI film growth on anode surface was highly attributable to cell degradation.

Keywords:Operating life estimation;Calendar life;Pulse power cycling;Pouch-type cells;Film growth model

[References]

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Belt JR, Ho CD, Motloch CG, Miller TJ, Duong TQ, J. Power Sources, 123(2), 241 (2003)
Kim JH, Jung MJ, Kim MJ, Lee YS, J. Ind. Eng. Chem., 61, 368 (2018)
Seo HR, Na SB, Lee BE, Yim TE, Oh SH, J. Ind. Eng. Chem., 64, 311 (2018)
Meng Q, Zhang Y, Dong P, Liang F, J. Ind. Eng. Chem., 61, 133 (2018)
Freedom Car Battery Test Manual for Power Assist Hybrid Electric Vehicle, DOEID, p. 11069 2003.
Neubauer J, Pesaran A, Bae C, Elder R, Cunningham B, J. Power Sources, 271, 614 (2014)
Kim D, Lee I, Kim J, Ryu JH, Son H, Ha KS, Yoon S, Bull. Korean Chem. Soc., 36, 2658 (2015)
Yoon S, Hwang I, Lee CW, Ko HS, Han KH, J. Electroanal. Chem., 655(1), 32 (2011)
Yoon S, Kim H, Oh SM, J. Power Sources, 94(1), 68 (2001)
Karner D, Francfort J, J. Power Sources, 174(1), 69 (2007)
Thackeray MM, Wolverton C, Isaacs ED, Energy Environ. Sci., 5, 7854 (2012)
Yoshida T, Takahashi M, Morikawa S, Ihara C, Katsukawa H, Shiratsuchi T, Yamaki J, J. Electrochem. Soc., 153(3), A576 (2006)
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Arora P, Popov BN, White RE, J. Electrochem. Soc., 145(3), 807 (1998)
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Jang DH, Oh SM, J. Electrochem. Soc., 144(10), 3342 (1997)

[1] Abraham DP, Liu J, Chen CH, Hyung YE, Stoll M, Elsen N, MacLaren S, Twesten R, Haasch R, Sammann E, Petrov I, Amine K, Henriksen G, J. Power Sources, 119, 511 (2003)

[2] Xia YY, Sakai T, Fujieda T, Yang XQ, Sun X, Ma ZF, McBreen J, Yoshio M, J. Electrochem. Soc., 148(7), A723 (2001)

[3] Thomas EV, Case HL, Doughty DH, Jungst RG, Nagasubramanian G, Roth EP, J. Power Sources, 124(1), 254 (2003)

[4] Belt JR, Ho CD, Motloch CG, Miller TJ, Duong TQ, J. Power Sources, 123(2), 241 (2003)

[5] Kim JH, Jung MJ, Kim MJ, Lee YS, J. Ind. Eng. Chem., 61, 368 (2018)

[6] Seo HR, Na SB, Lee BE, Yim TE, Oh SH, J. Ind. Eng. Chem., 64, 311 (2018)

[7] Meng Q, Zhang Y, Dong P, Liang F, J. Ind. Eng. Chem., 61, 133 (2018)

[8] Freedom Car Battery Test Manual for Power Assist Hybrid Electric Vehicle, DOEID, p. 11069 2003.

[9] Neubauer J, Pesaran A, Bae C, Elder R, Cunningham B, J. Power Sources, 271, 614 (2014)

[10] Kim D, Lee I, Kim J, Ryu JH, Son H, Ha KS, Yoon S, Bull. Korean Chem. Soc., 36, 2658 (2015)

[11] Yoon S, Hwang I, Lee CW, Ko HS, Han KH, J. Electroanal. Chem., 655(1), 32 (2011)

[12] Yoon S, Kim H, Oh SM, J. Power Sources, 94(1), 68 (2001)

[13] Karner D, Francfort J, J. Power Sources, 174(1), 69 (2007)

[14] Thackeray MM, Wolverton C, Isaacs ED, Energy Environ. Sci., 5, 7854 (2012)

[15] Yoshida T, Takahashi M, Morikawa S, Ihara C, Katsukawa H, Shiratsuchi T, Yamaki J, J. Electrochem. Soc., 153(3), A576 (2006)

[16] Choi W, Manthiram A, J. Electrochem. Soc., 154(8), A792 (2007)

[17] Arora P, Popov BN, White RE, J. Electrochem. Soc., 145(3), 807 (1998)

[18] Allen LRF, Bard J, Electochemical Methods: Fundamentals and Applications, John Wiley & Sons, Inc., 1998.

[19] Jang DH, Oh SM, J. Electrochem. Soc., 144(10), 3342 (1997)