화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.68, 311-324, December, 2018
DOI10.1016/j.jiec.2018.08.002  Export Citation
Neodymium doped mixed metal oxide derived from CoAl-layered double hydroxide: Considerable enhancement in visible light photocatalytic activity
Fatemeh Khodam1, Hamid Reza Amani-Ghadim2, Soheil Aber1, 3, Ali Reza Amani-Ghadim4, †, and Iraj Ahadzadeh5
  • 1Research Laboratory of Environmental Protection Technology, Faculty of Chemistry, Department of Applied Chemistry, University of Tabriz, Tabriz, Iran
  • 2Materials Engineering Faculty, Sahand University of Technology, Tabriz, Iran
  • 3Engineering Faculty, Near East University, 99138 Nicosia, Mersin 10, North Cyprus, Turkey
  • 4Research Laboratory of Applied Chemistry, Department of Chemistry, Faculty of Basic Science, Azarbaijan Shahid Madani University, P.O. Box 83714-161, Tabriz, Iran
  • 5Department of Physical Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran
E-mail:
Herein, the Neodymium ion (Nd3+) doped CoAl-LDH have been successfully prepared via co-precipitation method and was used as a precursor of Nd-doped CoAl-mixed metal oxides (MMO). The photocatalytic activity of doped LDH and MMO was investigated in the degradation of an azo dye, C.I. Acid Red 14, under visible light irradiation. DRS and PL analysis demonstrated decreasing in the band gap energy and recombination of photo-induced charge carriers of Nd-doped LDH and MMO compared with the pristine CoAL-LDH. Due to significant difference in photocatalytic performance. A power law empirical kinetic model was obtained for predicting the photocatalytic degradation efficiency.
Keywords:Layered double hydroxides;Mixed metal oxide;Photocatalyst;Electron-hole;Empirical kinetic model
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