화학공학소재연구정보센터
Korean Journal of Chemical Engineering, Vol.37, No.2, 189-208, February, 2020
Graphene-based 3D lightweight cellular structures: Synthesis and applications
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Ultralight three-dimensional (3D) cellular architectures are both a challenge and an opportunity for those academic and industrial applications involved with high performance material design. The challenges have been accessed by employing a variety of materials. Accordingly, graphene has shown greatest potential by virtue of its unique chemical, thermal, electronic, and mechanical properties for applications ranging from structural materials to energy storage/conversion devices. In this review, we highlight recent efforts and advances made in the implementation of graphene-based 3D cellular architectures, especially focusing on the ultralight density region (<10mgㆍcm-3). First, we reviewed the synthetic approaches for generating graphene-based 3D lightweight cellular structures according to the criteria of closed-cellular structures (CCSs) or open-cellular structures (OCSs) whether cell faces between constituent unit cells exist or not, respectively. These structural differences could lead to discerning physical properties, such as in mass transport across pores, heat/electron transfer through graphene framework, and various modes in mechanical deformation. We then collectively introduce recent achievements for representative applications utilizing different types of cellular structures such as flexible electronics, energy storage/conversion systems, fluid absorption, mechanical dampers, and sensors. Finally, we highlight the future perspectives of graphene-based lightweight cellular structures to surpass existing technological challenges.
  1. Stoller MD, Park S, Zhu Y, An J, Ruoff RS, Nano Lett., 8, 3498 (2008)
  2. Rao CNR, Sood AK, Subrahmanyam KS, Govindaraj A, Angew. Chem.-Int. Edit., 48, 7752 (2009)
  3. Balandin AA, Ghosh S, Bao W, Calizo I, Teweldebrhan D, Miao F, Lau CN, Nano Lett., 8, 902 (2008)
  4. Bolotin KI, Sikes KJ, Jiang Z, Klima M, Fudenberg G, Hone J, Kim P, Stormer HL, Solid State Commun., 146, 351 (2008)
  5. Zhang YB, Tan YW, Stormer HL, Kim P, Nature, 438, 201 (2005)
  6. Bonaccorso F, Sun Z, Hasan T, Ferrari AC, Nat. Photonics, 4, 611 (2010)
  7. Guan Y, Hu T, Wu J, Zhao L, Tian F, Pan W, He P, Qi X, Li F, Xu K, Korean J. Chem. Eng., 39, 115 (2016)
  8. Chen ZP, Ren WC, Gao LB, Liu BL, Pei SF, Cheng HM, Nat. Mater., 10(6), 424 (2011)
  9. Lee C, Wei X, Kysar JW, Hone J, Science, 321, 5887 (2008)
  10. Li D, Muller MB, Gilje S, Kaner RB, Wallace GG, Nat. Nanotechnol., 3(2), 101 (2008)
  11. Stankovich S, Dikin DA, Piner RD, Kohlhaas KA, Kleinhammes A, Jia Y, Wu Y, Nguyen ST, Ruoff RS, Carbon, 45, 1588 (2007)
  12. Li X, Cai W, An J, Kim S, Nah J, Yang D, Piner R, Velamakanni A, Jung I, Tutuc E, Banerjee SK, Colombo L, Ruoff RS, Science, 324, 1312 (2009)
  13. Marcano DC, Kosynkin DV, Berlin JM, Sunitskii A, Sun Z, Slesarev A, Alemany LB, Lu W, Tour JM, ACS Nano, 4, 4806 (2010)
  14. Lee JH, Lee EK, Joo WJ, Jang Y, Kim BS, Lim JY, Choi SH, Ahn SJ, Ahn JR, Park MH, Yang CW, Choi BL, Hwang SW, Whang D, Science, 344(6181), 286 (2014)
  15. Chen ZP, Ren WC, Gao LB, Liu BL, Pei SF, Cheng HM, Nat. Mater., 10(6), 424 (2011)
  16. Hong JY, Bak BM, Wie JJ, Kong J, Park HS, Adv. Funct. Mater., 25(7), 1053 (2015)
  17. Kim SC, Park YK, Kim BH, Kim HG, Lee WJ, Lee H, Jung SC, Korean J. Chem. Eng., 35(3), 750 (2018)
  18. Park SK, Nakhanivej P, Park HS, Korean J. Chem. Eng., 36(10), 1557 (2019)
  19. Zhang B, Zhang J, Sang X, Liu C, Luo T, Peng L, Han B, Tan X, Ma X, Wang D, Zhao N, Sci. Rep., 6, 25830 (2016)
  20. Huynh TTK, Tran TQN, Yoon HH, Kim WJ, Kim IT, Korean J. Chem. Eng., 36(7), 1193 (2019)
  21. Barakat MAEF, Kumar R, Al-Makishah NH, Neamtallah AA, Alafif ZO, Korean J. Chem. Eng., 36(8), 1281 (2019)
  22. Abbasi F, Karimi-Sabet J, Ghotbi C, Abbasi Z, Korean J. Chem. Eng., 35(5), 1174 (2018)
  23. Noh MJ, Oh MJ, Choi JH, Yu JC, Kim WJ, Park J, Chang YW, Yoo PJ, Soft Matter, 14, 6708 (2018)
  24. Bi HC, Xie X, Yin KB, Zhou YL, Wan S, He LB, Xu F, Banhart F, Sun LT, Ruoff RS, Adv. Funct. Mater., 22(21), 4421 (2012)
  25. Kazeem TS, Zubair M, Daud M, Mu’azu ND, Al-Harthi MA, Korean J. Chem. Eng., 36(7), 1057 (2019)
  26. Tahmasebi F, Alimohammadi M, Nabizadeh R, Khoobi M, Karimian K, Zarei A, Korean J. Chem. Eng., 6, 894 (2019)
  27. Mirzazadeh H, Lashanizadegan M, Korean J. Chem. Eng., 35(3), 684 (2018)
  28. Ni N, Barg S, Garcia-Tunon E, Perez FM, Miranda M, Lu C, Mattevi C, Saiz E, Sci. Rep., 5, 13712 (2015)
  29. Qin Y, Peng Q, Ding Y, Lin Z, Wang C, Li Y, Xu F, Li J, Yuan Y, He X, Li Y, ACS Nano, 9, 8933 (2015)
  30. Kim KS, Lim SR, Kim SE, Lee JY, Chung CH, Choe WS, Yoo PJ, Sens. Actuators B-Chem., 242, 1121 (2017)
  31. Lee YS, Kim JM, Koo JH, KiM TH, Kim DH, Korean J. Chem. Eng., 35(1), 1 (2018)
  32. Novoselov KS, McCann E, Morozov SV, Falko VI, Katsnelson MI, Zeitler U, Jiang D, Schedin F, Geim AK, Nat. Phys., 2, 177 (2006)
  33. Kim KS, Zhao Y, Jang H, Lee SY, Kim JM, Kim KS, Ahn JH, Kim P, Choi JY, Hong BH, Nature, 457, 706 (2009)
  34. Wan D, Yang C, Tang Y, Zhou M, Zhong Y, Huang F, Lin J, ACS Nano, 6, 9068 (2012)
  35. Gibson LJ, Ashby MF, Harley BA, Cellular Materials in Nature and Medicine, Cambridge University Press, Cambridge, UK (2010).
  36. Gibson LJ, J. Biomech., 38, 377 (2005)
  37. Schaedler TA, Jacobsen AJ, Torrents A, Sorensen AE, Lian J, Greer JR, Valdevit L, Carter WB, Science, 334(6058), 962 (2011)
  38. Husing N, Schubert U, Angew. Chem.-Int. Edit., 37, 22 (1998)
  39. Pierre AC, Pajonk GM, Chem. Rev., 102(11), 4243 (2002)
  40. Kuang J, Liu L, Gao Y, Zhou D, Chen Z, Han B, Zhang Z, Nanoscale, 5, 12171 (2013)
  41. Sun HY, Xu Z, Gao C, Adv. Mater., 25(18), 2554 (2013)
  42. Zhou Y, Bao Q, Tang LAL, Zhong Y, Loh KP, Chem. Mater., 21, 2950 (2009)
  43. Xu Y, Sheng K, Li C, Shi G, ACS Nano
  44. Wu Y, Yi N, Huang L, Zhang T, Fang S, Chang H, Li N, Oh J, et al., Nat. Commun., 6, 7141 (2015)
  45. Qiu L, Liu JZ, Chang SLY, Wu Y, Li D, Nat. Commun., 3, 1241 (2012)
  46. Hunter CA, Sanders JKM, J. Am. Chem. Soc., 112, 5525 (1990)
  47. Chen W, Yan L, Nanoscale, 3, 3132 (2011)
  48. Zhang L, Chen G, Hedhili MN, Zhanga H, Wang P, Nanoscale, 4, 7038 (2012)
  49. Zhang X, Sui Z, Xu B, Yue S, Luo Y, Zhanc W, Liuc B, J. Mater. Chem., 21, 6494 (2011)
  50. Liu T, Huang M, Li X, Wang C, Gui CX, Yu ZZ, Carbon, 100, 456 (2016)
  51. Xie X, Zhou Y, Bi H, Yin K, Wan S, Sun L, Sci. Rep., 3, 2117 (2013)
  52. Hu H, Zhao ZB, Wan WB, Gogotsi Y, Qiu JS, Adv. Mater., 25(15), 2219 (2013)
  53. Hong JY, Sohn EH, Park S, Park HS, Chem. Eng. J., 269, 229 (2015)
  54. Zhao Y, Hu C, Hu Y, Cheng H, Shi G, Qu L, Angew. Chem.-Int. Edit., 51, 11371 (2012)
  55. Vinod S, Tiwary CS, da Silva Autreto PA, Taha-Tijerina J, Ozden S, Chipara AC, Vajtai R, Galvao DS, Narayanan TN, Ajayan PM, Nat. Commun., 5, 4541 (2014)
  56. Hence LL, West JK, Chem. Rev., 90, 33 (1990)
  57. Worsley MA, Pauzauskie PJ, Olson TY, Biener J, Satcher JH, Baumann TF, J. Am. Chem. Soc., 132(40), 14067 (2010)
  58. Worsley MA, Olson TY, Lee JRI, Willey TM, Nielsen MH, Roberts SK, Pauzauskie PJ, Biener J, Satcher JH, Baumann TF, J. Phys. Chem. Lett., 2, 921 (2011)
  59. Meng F, Zhang X, Xu B, Yue S, Guo H, Luo Y, J. Mater. Chem., 21, 18537 (2011)
  60. Reina A, Jia X, Ho J, Nezich D, Son H, Bulovic V, Dresselhaus MS, Kong J, Nano Lett., 9, 30 (2009)
  61. Mecklenburg M, Schuchardt A, Mishra YK, Kaps S, Adelung R, Lotnyk A, Kienle L, Schulte K, Adv. Mater., 24(26), 3486 (2012)
  62. Bi H, Chen IW, Lin TQ, Huang FQ, Adv. Mater., 27(39), 5943 (2015)
  63. Garcia-Tunon E, Barg S, Franco J, Bell R, Eslava S, D'Elia E, Maher RC, Guitian F, Saiz E, Adv. Mater., 10, 1688 (2015)
  64. Zhu C, Han TYJ, Duoss EB, Golobic AM, Kuntz JD, Spadaccini CM, Worsley MA, Nat. Commun., 6, 6962 (2015)
  65. Lin Y, Liu F, Casano G, Bhavsar R, Kinloch IA, Derby B, Adv. Mater., 28(36), 7993 (2016)
  66. Zhang, Zhang F, Medarametla SP, Li H, Zhou C, Lin D, Small, 12, 1702 (2016)
  67. Zhang Q, Zhang F, Xu X, Zhou C, Lin D, ACS Nano, 12, 1096 (2018)
  68. Kim J, Cote LJ, Kim F, Yuan W, Shull KR, Huang JX, J. Am. Chem. Soc., 132(23), 8180 (2010)
  69. Kim F, Cote LJ, Huang JX, Adv. Mater., 22(17), 1954 (2010)
  70. Sun ZW, Feng T, Russell TP, Langmuir, 29(44), 13407 (2013)
  71. Li YR, Chen J, Huang L, Li C, Hong JD, Shi GQ, Adv. Mater., 26(28), 4789 (2014)
  72. Barg S, Perez FM, Ni N, do Vale Pereira P, Maher RC, Garcia-Tunon E, Eslava S, Agnoli S, Mattevi C, Saiz E, Nat. Commun., 5, 4328 (2014)
  73. Bao C, Bi S, Zhang H, Zhao J, Wang P, Yue CY, Yang J, J. Mater. Chem. A, 4, 9437 (2016)
  74. Zhao X, Yao W, Gao W, Chen H, Gao C, Adv. Mater., 29, 170148 (2017)
  75. Inagaki M, Qiu J, Guo Q, Carbon, 87, 128 (2015)
  76. Costeux S, J. Appl. Polym. Sci., 131, 41293 (2014)
  77. Wang X, Zhang Y, Zhi C, Wang X, Tang D, Xu Y, Weng Q, Jiang X, Mitome M, Golberg D, Bando Y, Nat. Commun., 4, 2905 (2013)
  78. McDonald JC. Whitesides GM, Accounts Chem. Res., 35, 491 (2002)
  79. Shah RK, Shum HC, Rowat AC, Lee D, Agresti JJ, Utada AS, Chu LY, Kim JW, Fernandez-Nieves A, Martinez CJ, Weitz DA, Mater. Today, 11, 18 (2008)
  80. Yeo SJ, Oh MJ, Jun HM, Lee M, Bae JG, Kim Y, Park KJ, Lee S, Lee D, Weon BM, Lee WB, Kwon SJ, Yoo PJ, Adv. Mater., 30, 180299 (2018)
  81. Tang G, Jiang G, Li X, Zhang H, Dasari A, Yu Z, Carbon, 77, 592 (2014)
  82. Zhang Q, Wang Y, Zhang B, Zhao K, He P, Huang B, Carbon, 127, 449 (2018)
  83. Li C, Jiang D, Liang H, Huo B, Liu C, Yang W, Liu J, Adv. Funct. Mater., 28, 170467 (2018)
  84. Ji HX, Zhang LL, Pettes MT, Li HF, Chen SS, Shi L, Piner R, Ruoff RS, Nano Lett., 12, 2446 (2012)
  85. Liu T, Kavian R, Kim I, Lee SW, J. Phys. Chem. Lett., 5, 4324 (2014)
  86. Liu T, Lee B, Kim BG, Lee MJ, Park J, Lee SW, Small, 14, 180123 (2018)
  87. Zheng WC, Fan HL, Wang L, Jin ZX, Langmuir, 31(42), 11671 (2015)
  88. Worsley MA, Kucheyev SO, Mason HE, Merrill MD, et al., Chem. Commun., 48, 8428 (2012)
  89. Yang J, Qi GQ, Bao RY, Yi K, Li M, Peng L, Cai Z, Yang MB, Wei D, Yang W, Energy Storage Mater., 13, 88 (2018)
  90. Li G, Hong G, Dong D, Song W, Zhang X, Adv. Mater., 30, 180175 (2018)
  91. Lu KQ, Xin X, Zhang N, Tang ZR, Xu YJ, J. Mater. Chem. A, 6, 4590 (2018)
  92. Li X, Yu J, Wageh S, Al-Ghamdi AA, Xie J, Small, 12, 6640 (2016)
  93. Fan YY, Ma WG, Han DX, Gan SY, Dong XD, Niu L, Adv. Mater., 27(25), 3767 (2015)
  94. Tsang CHA, Tobin J, Xuan J, Vilela F, Huang HB, Leung DYC, Appl. Catal. B: Environ., 240, 50 (2019)
  95. Hou CY, Zhang QH, Li YG, Wang HZ, J. Hazard. Mater., 205, 229 (2012)
  96. Wong YL, Tobin JM, Xu Z, Vilela F, J. Mater. Chem. A, 4, 18677 (2016)
  97. Yang J, Shi Q, Zhang R, Xie M, Jiang X, Wang F, Cheng X, Han W, Carbon, 138, 118 (2018)
  98. Zhang RY, Ma MZ, Zhang Q, Dong F, Zhou Y, Appl. Catal. B: Environ., 235, 17 (2018)
  99. Zhang RY, Huang ZA, Li CJ, Zuo YS, Zhou Y, Appl. Surf. Sci., 475, 953 (2019)
  100. Li X, Yu J, Low J, Fang Y, Xiao J, Chen X, J. Mater. Chem. A, 3, 2485 (2015)
  101. Lu Y, Ma B, Yang Y, Huang E, Ge Z, Zhang T, Zhang S, Li L, Guan N, Ma Y, Chen Y, Nano Res., 10, 1662 (2017)
  102. Lu Y, Yang Y, Zhang T, Ge Z, Chang H, Xiao P, Xie Y, Hua L, Li Q, Li H, ACS Nano, 10, 10507 (2016)
  103. Long R, English NJ, Prezhdo OV, J. Am. Chem. Soc., 134(34), 14238 (2012)
  104. Yan Y, Wang C, Yan X, Xiao L, He J, Gu W, Shi W, J. Phys. Chem. C, 118, 23519 (2014)
  105. Pan JQ, Wang BB, Dong ZJ, Zhao C, Jiang ZY, Song CS, Wang JJ, Zheng YY, Li CR, Int. J. Hydrog. Energy, 44(36), 19942 (2019)
  106. Ho DH, Jun HM, Yeo SJ, Hong P, Oh MJ, Weon BM, Lee WB, Kwon SJ, Yoo PJ, Cho JH, J. Phys. Chem. C, 123, 9884 (2019)
  107. Wang CH, Chen X, Wang B, Huang M, Wang B, Jiang Y, Ruoff RS, ACS Nano, 12, 5816 (2018)
  108. Guo F, Zheng X, Liang C, Jiang Y, Xu Z, Jiao Z, Liu Y, Wang HT, Sun H, Ma L, Gao W, Greiner A, Agarwal S, Gao C, ACS Nano, 13, 5549 (2019)
  109. Lendlein A, Kelch S, Angew. Chem.-Int. Edit., 41, 2034 (2002)
  110. Wang ZL, Mater. Today, 10, 20 (2007)
  111. Ogawa Y, Ando D, Sutou Y, Koike J, Science, 353(6297), 368 (2016)
  112. Xie Y, Han M, Wang R, Zobeiri H, Deng X, Zhang P, Wang X, ACS Nano, 13, 5385 (2019)
  113. Mu X, Wu X, Zhang T, Go DB, Luo T, Sci. Rep., 4, 3909 (2014)
  114. Li G, Dong D, Hong G, Yan L, Zhang X, Song W, Adv. Mater., 31, 190140 (2019)
  115. Sun HT, Mei L, Liang JF, Zhao ZP, Lee C, Fei HL, Ding MN, Lau J, Li MF, Wang C, Xu X, Hao GL, Papandrea B, Shakir I, Dunn B, Huang Y, Duan XF, Science, 356(6338), 599 (2017)
  116. Chung DDL, Carbon, 39, 279 (2001)
  117. Fang Z, Li C, Sun J, Zhang H, Zhang J, Carbon, 45, 2873 (2007)
  118. Chen ZP, Xu C, Ma CQ, Ren WC, Cheng HM, Adv. Mater., 25(9), 1296 (2013)
  119. Wu S, Zou M, Li Z, Chen D, Zhang H, Yuan Y, Pei Y, Cao A, Small, 14, 180063 (2018)
  120. Huangfu Y, Liang C, Han Y, Qiu H, Song P, Wang L, Kong J, Gu J, Compos. Sci. Technol., 169, 70 (2019)
  121. Liu X, Chen T, Liang H, Qin F, Yang H, Guo X, RSC Adv., 9, 27 (2019)
  122. Xi J, Li Y, Zhou E, Liu Y, Gao W, Guo Y, Ying J, Chen Z, Chen G, Gao C, Carbon, 135, 44 (2018)
  123. Hu C, Xue J, Dong L, Jiang Y, Wang X, Qu L, Dai L, ACS Nano, 10, 1325 (2016)
  124. Wicklein B, Kocjan A, Salazar-Alvarez G, Carosio F, Camino G, Antonietti M, Bergstrom L, Nat. Nanotechnol., 10(3), 277 (2015)