화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.84, 332-339, April, 2020
DOI10.1016/j.jiec.2020.01.015  Export Citation
Organosilicate compound filler to increase the mechanical strength of superhydrophilic layer-by-layer assembled film
Sungwon Jung, Sohyeon Park, Woojin Choi, Jiwoong Heo, Jaesung Kwon1, Sunghwan Choi2, and Jinkee Hong†
  • Department of Chemical & Biomolecular Engineering, College of Engineering, Yonsei University, 50 Yonsei Ro, Seodaemun Gu, Seoul 03722, Republic of Korea
  • 1Department and Research Institute of Dental Biomaterials and Bioengineering, College of Dentistry, Yonsei University, 50 Yonsei Ro, Seodaemun Gu, Seoul 03722, Republic of Korea
  • 2Department of Orthodontics, Institute of Craniofacial Deformity, College of Dentistry, Yonsei University, 50 Yonsei Ro, Seodaemun Gu, Seoul 03722, Republic of Korea
E-mail:
Technologies that can overcome the poor mechanical properties of the coatings with bacterial anti-adhesion effect based on super-wetting properties are still challenging. In this study, we developed a durable superhydrophilic nanocomposite coatings composed of polysaccharide matrix and organosilicate (OS) compound filler. In brief, carboxymethylcellulose (CMC) and chitosan (CS)-based multilayer films were fabricated via Layer-by-layer (LbL) assembly then crosslinking for the films was performed to improve inner stability and induce superhydrophilicity. As second step, we synthesized a biocompatible and robust organosilicate compound via sol-gel reaction and incorporate it as reinforcing filler into the superhydrophilic films. Consequently, durable hybrid superhydrophilic nanocomposites were coated on the substrate, and various chemical analysis and performance evaluations of the coatings were performed. The mechanical properties of the composite coatings were significantly improved due to the OS acting as a reinforcing filler in the multilayer films. Furthermore, the coatings exhibited excellent biocompatibility and transparency and exerted antibacterial effect based on superhydrophilic property. This study presents a practical strategy to solve the poor durability, the limitation of super-wetting coatings widely applied in various fields.
Keywords:Superhydrophilic surface;Organosilicate;Compound filler;Antibacterial effect;High mechanical strength
  1. Park S, Kim HH, Yang SB, Moon JH, Ahn HW, Hong J, ACS Appl. Mater. Interfaces, 10, 17714 (2018)
  2. Latremouille C, Carpentier A, Leprince P, Roussel JC, Cholley B, Boissier E, Epailly E, Capel A, Jansen P, Smadja DM, J.HeartLung Transplant., 37, 33 (2018)
  3. Sasso ED, Bagno A, Scuri ST, Gerosa G, Iop L, Annu. Rev. Biomed. Eng., 21 (2019)
  4. Suzuki A, Murakami T, Encycl.BiocolloidBiointerfaceSci., 269.2702VSet (2016).
  5. Meng Y, Ye L, Coates P, Twigg P, J. Phys. Chem., 122, 3157 (2018)
  6. Yu Q, Wu Z, Chen H, Acta Biomater, 16, 1 (2015)
  7. Krishnamoorthy M, Hakobyan S, Ramstedt M, Gautrot JE, Chem. Rev., 114(21), 10976 (2014)
  8. Park S, Park J, Heo J, Lee SE, Shin JW, Chang M, Hong J, J. Ind. Eng. Chem. (2018).
  9. Pranantyo D, Xu LQ, Kang ET, Chan-Park MB, Biomacromolecules (2018).
  10. Vaterrodt A, Thallinger B, Daumann K, Koch D, Guebitz GM, Ulbricht M, Langmuir, 32(5), 1347 (2016)
  11. Hwang GB, Page K, Patir A, Nair SP, Allan E, Parkin IP, ACS Nano (2018).
  12. Cheng X, Li R, Du J, Sheng J, Ma K, Ren X, Huang TS, Polym. Adv. Technol., 26, 99 (2015)
  13. Park S, Choi D, Jeong H, Heo J, Hong J, Mol. Pharmaceutics, 14, 3322 (2017)
  14. Gong SQ, Niu LN, Kemp LK, Yiu CK, Ryou H, Qi YP, Blizzard JD, Nikonov S, Brackett MG, Messer RL, Acta Biomater., 8, 3270 (2012)
  15. Ivanova K, Fernandes MM, Francesko A, Mendoza E, Guezguez J, Burnet M, Tzanov T, ACS Appl. Mater. Interfaces, 7, 27066 (2015)
  16. Wang J, Chen Y, Chen Y, Li J, Colloid Polym. Sci., 295, 2191 (2017)
  17. Tripathy A, Kumar A, Sreedharan S, Muralidharan G, Pramanik A, Nandi D, Sen P, ACS Biomater. Sci. Eng., 4, 2213 (2018)
  18. Choi M, Xiangde L, Park J, Choi D, Heo J, Chang M, Lee C, Hong J, Chem. Eng. J., 309, 463 (2017)
  19. Zhang M, Wang P, Sun H, Wang Z, ACS Appl. Mater. Interfaces., 6, 22108 (2014)
  20. Otitoju TA, Ahmad AL, Ooi BS, J. Ind. Eng. Chem., 47, 19 (2017)
  21. Qian HC, Yang JZ, Lou YT, Rahman OU, Li ZY, Ding X, Gao J, Du CW, Zhang DW, Appl. Surf. Sci., 465, 267 (2019)
  22. Li L, Zhang G, Su Z, Angew. Chem.-Int. Edit., 55, 9093 (2016)
  23. Ma D, Peh SB, Han G, Chen SB, ACS Appl. Mater. Interfaces., 9, 7523 (2017)
  24. Cho H, Lee J, Lee S, Hwang W, Phys. Chem. Chem. Phys., 17, 6786 (2015)
  25. Wang CF, Tzeng FS, Chen HG, Chang CJ, Langmuir, 28(26), 10015 (2012)
  26. Croissant JG, Cattoen X, Durand JO, Man MWC, Khashab NM, Nanoscale, 8, 19945 (2016)
  27. Lin X, Hwangbo S, Jeong H, Cho YA, Ahn HW, Hong J, J. Ind. Eng. Chem., 36, 30 (2016)
  28. Ghanbari H, Cousins BG, Seifalian AM, Macromol. Rapid Commun., 32(14), 1032 (2011)
  29. Zhang HY, Oyanedel-Craver V, J. Hazard. Mater., 260, 272 (2013)
  30. Dangseeyun N, Supaphol P, Nithitanakul M, Polym. Test., 23, 187 (2004)
  31. Stojanovic DB, Brajovic L, Orlovic A, Dramlic D, Radmilovic V, Uskokovic PS, Aleksic R, Prog. Org. Coat., 76, 626 (2013)
  32. Swamy BY, Yun YS, Int. J. Biol. Macromol., 77, 114 (2015)
  33. Zhang S, Liu W, Liang J, Li X, Liang W, He S, Zhu C, Mao L, Cellulose, 20, 1135 (2013)
  34. Wu T, Farnood R, Carbohydr. Polym., 114, 500 (2014)
  35. Nuraje N, Asmatulu R, Cohen RE, Rubner MF, Langmuir, 27, 782 (2010)
  36. Lundin M, Solaqa F, Thormann E, Macakova L, Blomberg E, Langmuir, 27(12), 7537 (2011)
  37. Richert L, Boulmedais F, Lavalle P, Mutterer J, Ferreux E, Decher G, Schaaf P, Voegel JC, Picart C, Biomacromolecules, 5(2), 284 (2004)
  38. Cho KL, Hill AJ, Caruso F, Kentish SE, Adv. Mater., 27(17), 2791 (2015)
  39. Branca C, D'Angelo G, Crupi C, Khouzami K, Rifici S, Ruello G, Wanderlingh U, Polymer, 99, 614 (2016)
  40. Mi FL, Sung HW, Shyu SS, Carbohydr. Polym., 48, 61 (2002)
  41. Bai RQ, Qiu T, Han F, He LF, Li XY, Appl. Surf. Sci., 258(19), 7683 (2012)
  42. Choi SS, Lee AS, Lee HS, Jeon HY, Baek KY, Choi DH, Hwang SS, J. Polym. Sci. A: Polym. Chem., 49(23), 5012 (2011)
  43. Choi SS, Lee AS, Hwang SS, Baek KY, Macromolecules, 48(17), 6063 (2015)
  44. Adera S, Raj R, Enright R, Wang EN, Nat. Commun., 4, 2518 (2013)
  45. Kobayashi M, Terayama Y, Yamaguchi H, Terada M, Murakami D, Ishihara K, Takahara A, Langmuir, 28(18), 7212 (2012)
  46. Tijing LD, Ruelo MTG, Amarjargal A, Pant HR, Park CH, Kim DW, Kim CS, Chem. Eng. J., 197, 41 (2012)
  47. Zhang P, Lin L, Zang D, Guo X, Liu M, Small, 13, 150333 (2017)
  48. Younas H, Fei Y, Shao J, He Y, Biofouling, 32, 1089 (2016)