화학공학소재연구정보센터
Polymer(Korea), Vol.44, No.2, 154-162, March, 2020
2,2′-Bis[4-(6-amino-3-pyridinoxy) phenyl] Propane에서 유도된 새로운 폴리이미드 합성 및 분석
Synthesis and Characterization of Novel Polyimides Derived from 2,2′-Bis[4-(6-amino-3-pyridinoxy) phenyl] Propane
E-mail:
A novel pyridine-containing aromatic diamine monomer, 2,2′-bis[4-(6-amino-3-pyridinoxy) phenyl] propane, was synthesized through nucleophilic substitution reaction. A series of polyimides (PIs) were obtained by the polycondensation reaction of synthesized monomer with four commercial dianhydrides. The structure and properties of the resulting PIs were characterized by Fourier transform infrared spectroscopy, differential scanning calorimetric analysis, dynamic mechanical thermal analysis, thermogravimetric analysis, and X-ray diffraction. The PIs exhibited good thermal stability with glass transition temperature of 231 to 303 °C by DSC and 205 to 274 °C by DMA. The temperature at 5% weight loss was 478 to 501 °C in nitrogen atmosphere, and the residual mass range at 800 °C was 42-55%. The excellent mechanical properties included tensile strength of 98-102 MPa, elongation at break of 6-18%, and tensile modulus of 2.8-3.0 GPa. The cut-off wavelength ranged from 391-440 nm, indicating that the resulting PIs had desirable optical performance.
  1. Liaw DJ, Wang KL, Huang YC, Lee KR, Lai JY, Ha CS, Prog. Polym. Sci, 37, 907 (2012)
  2. Zhou YT, Liu XL, Wei MH, Song C, Huang ZZ, Sheng SR, Polym. Bull., 11, 1 (2018)
  3. Hu QB, Zhang L, Dai RJ, Ru JH, Wu HK, Insulating Mater., 50, 30 (2017)
  4. Cihanoglu A, Altinkaya SA, Sep. Purif. Technol., 207, 353 (2018)
  5. Bell VL, Stump BL, Gager H, J. Polym. Sci. A: Polym. Chem., 14, 2275 (2010)
  6. Sheng DD, Wang HT, Ying ZH, Plastics, 42, 46 (2013)
  7. Meddeb AB, Ounaies Z, Lanagan M, Chem. Phys. Lett., 649, 111 (2016)
  8. Lee YS, Lee SK, Kim JH, Yoon KH, Polym. Korea, 43(3), 331 (2019)
  9. Yu YY, Huang TJ, Lee WY, Chen YC, Kuo CC, Org. Electron., 48, 19 (2017)
  10. Escorihuela S, Tena A, Shishatskiy S, Escolastico S, Brinkmann T, Serra JM, Abetz V, Membranes, 8, 16 (2018)
  11. Jiang ZQ, Wang TT, Wu FP, Lin JD, Liao LS, J. Mater. Chem. A, 36, 17256 (2018)
  12. Song GL, Zhang Y, Wang DM, Chen CH, Zhou HW, Zhao XG, Dang GD, Polymer, 54(9), 2335 (2013)
  13. Tian H, Kuang XY, Mao AJ, Yang Y, Xu C, Sayedaghaee SO, Bellaiche L, Phys. Rev. B, 97, 020103 (2018)
  14. Chen B, Li H, Huang X, Wei C, Chin. J. Chem., 35, 341 (2017)
  15. Jun J, Lee JH, Choi HJ, Moon S, Kim ID, Lee H, Appl. Surf. Sci., 423, 881 (2017)
  16. Zhang H, Shao LS, Gong SM, Gong Q, Wang YH, Chin. J. Liq. Cryst. Displays, 31, 258 (2016)
  17. Lee GG, Lee HM, Kim YH, Polym. Korea, 43(1), 113 (2019)
  18. Li YQ, Fang RC, Zheng AM, Chu YY, Tao X, Xu HH, Ding SJ, Shen YZ, J. Mater. Chem., 21, 15643 (2011)
  19. Yang WJ, Chang JH, Polym. Korea, 40(3), 405 (2016)
  20. Huang X, Pei X, Wang L, Mei M, Liu C, Wei C, J. Appl. Polym. Sci., 133, 43266 (2016)
  21. Qiao XY, Chung TS, AIChE J., 52, 3462 (2010)
  22. Oikawa E, Nozawa H, Polym. Bull., 13, 481 (1985)
  23. Mehdipour-Ataeia S, Nami M, Eur. Polym. J., 41, 1024 (2005)
  24. Kim J, Jeon HG, Kang P, Jeong KS, Chem. Commun., 53, 6508 (2017)
  25. Sanchez AM, Andrews J, Hussein I, Bennett GN, San KY, Biotechnol. Progr., 22, 420 (2010)
  26. Weller KJ, Gray SD, Briggs PM, Wigley DE, Organometallics, 14, 5588 (2002)
  27. Zhao L, Kou K, Zhuo L, Wang Y, Chin. Plastics, 27, 57 (2013)
  28. Chen SX, Pan HY, Chang ZH, Jin M, Pu HT, Ionics, 7, 1 (2018)
  29. Yao J, Wang C, Tian C, Zhao X, Zhou H, Wang D, Chen CH, Des. Monomers Polym., 20, 449 (2017)
  30. Cannella AF, Dey SK, Macmillan SN, Lacy DC, Dalton Trans., 47, 5171 (2018)
  31. Li Z, Wen Y, Wang Y, Zhu SM, High Perform. Polym., 29, 161 (2016)
  32. Snyder RW, Thomson B, Bartges B, Czerniawski D, Painter PC, Macromolecules, 22, 4166 (1989)
  33. Fernandez FDM, Jang JW, Yim JH, Polym. Korea, 43(3), 420 (2019)
  34. Guan Y, Wang D, Song G, Zhang X, Chen C, Zhou H, Dang G, Zhao X, High Perform. Polym., 26, 455 (2014)
  35. Xu YX, Chen CX, Zhang PX, Sun BH, Li JD, J. Chem. Eng. Data, 51(5), 1841 (2006)
  36. Zhang YH, Luo P, Yao HY, Guan SW, React. Funct. Polym., 72(9), 621 (2012)
  37. Zhou YT, Liu XL, Wei MH, Song C, Huang ZZ, Sheng SR, Polym. Bull., 11, 1 (2018)
  38. Guan Y, Wang DM, Song GL, Dang GD, Chen CH, Zhou HW, Zhao XG, Polymer, 55(16), 3634 (2014)