화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Applied Chemistry for Engineering, Vol.32, No.3, 229-236, June, 2021
DOI10.14478/ace.2021.1036  Export Citation
전기화학적 방법을 통한 금속 유기 골격체 합성
Electrochemical Synthesis of Metal-organic Framework
문상현1, †, 김지영2, †, 최현국2, 김문갑2, 이영세2, 이기영1, 2, †
  • 1경북대학교 미래과학기술융합학과
  • 2경북대학교 나노소재공학부
Sanghyeon Moon1, †, Jiyoung Kim2, †, Hyun-Kuk Choi2, Moon-Gab Kim2, Young-Sei Lee2, and Kiyoung Lee1, 2, †
  • 1Department of Advanced Science and Technology Convergence, Kyungpook National University, Sangju 37224, South Korea
  • 2School of Nano & Materials Science and Engineering, Kyungpook National University, Sangju 37224, South Korea
E-mail:, ,
초록
금속 유기 골격체는 최근 20년간 센서, 촉매, 에너지 저장과 같은 많은 응용분야에서 관심을 받아온 물질이다. 이 물질을 합성하기 위해 수열 합성, 유기용매열과 같은 합성법이 제시되어 왔으나, 그 공정이 복잡하면서 고비용.장시간이 소요된다는 문제점이 제기되어 왔다. 이를 해결하기 위한 전기화학적 합성법이 새롭게 제시되었는데, 간단한 준비절차와 특정한 온도.압력 조건 없이 합성할 수 있어 기존 합성법의 단점을 보완한다는 특징이 있다. 이에 본 총설논문에서는 전기화학적으로 합성 가능한 금속 유기 골격체의 종류와 전기화학적 합성 메커니즘을 다루고 있다. 전기화학적 합성법을 통해 형성된 금속 유기 골격체를 적용한 응용분야 연구동향을 정리하였다.
During the last two decades, metal-organic frameworks (MOFs) have been drawn attention due to their high specific surface area, porosity, and catalytic activities that allow to use in many applications such as sensor, catalysis, energy storage, etc. To synthesize MOFs hydrothermal or solvothermal method were generally used. However, these methods require high-cost equipment and long time-spend for the synthesis with multi-step process. In contrast, electrochemical synthesis has been considered as a simple and easy process under the ambient conditions. In this review, we described the mechanism of electrochemical MOFs synthesis by the number of configured electrodes system, with the recent reports of various applications.
Keywords:Metal-organic frameworks;Electrochemical synthesis;Anodic oxidization;Cathodic reduction;Thin film
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