화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.38, No.8, 1676-1685, August, 2021
DOI10.1007/s11814-021-0799-z  Export Citation
Construction of OH sites within MIL-101(Cr)-NH2 framework for enhanced CO2 adsorption and CO2/N2 selectivity
The Ky Vo†, Pham Van Vu, Van Cuong Nguyen, and Jinsoo Kim1, †
  • Department of Chemical Engineering, Industrial University of Ho Chi Minh City, 12 Nguyen Van Bao, Go Vap, Ho Chi Minh City, Vietnam
  • 1Department of Chemical Engineering (Integrated Engineering), Kyung Hee University, 1732 Deogyeong-daero, Giheung-gu, Yongin-si, Gyeonggi-do 17104, Korea
E-mail:,
The MIL-101(Cr)-NH2 framework was effectively modified by 2,5-dihydroxyterephthalic acid ((HO)2BDC) guest molecules to obtain (HO)2BDC-incorporated MIL-101(Cr)-NH2 adsorbent, namely (HO)2BDC@CrN. The CO2- temperature programmed-desorption (TPD) analysis indicated that the incorporation of (HO)2BDC into the MIL- 101(Cr)-NH2 framework generated new OH sites besides unsaturated Cr- metal sites and NH2 sites. The formed OH sites improved CO2 adsorption and separation on the prepared adsorbent. The highest CO2 uptake capacity of ~3.58mmol g-1 obtained over the novel (HO)2BDC@CrN adsorbent was higher 40% than that of the parent MOF, and also surpasses that of other previously reported adsorbents, including activated carbon, nitrogen-doped hollow carbon, zeolite, ZIF-68, MOF-5, ZIF-8, UiO-66(Zr), and MIL-100(Cr). The highest ideal adsorbed solution theory (IAST) CO2/ N2 selectivity of ~67 was obtained over the (HO)2BDC@CrN adsorbent at 100 kPa. The achieved selectivity was six times greater than that of pure MIL-101(Cr)-NH2. In addition, the synthesized (HO)2BDC@CrN adsorbent displayed good regenerability after six consecutive adsorption-desorption cycles.
Keywords:CO2 Adsorption;MIL-101(Cr)-NH2;Dihydroxyterephthalic Acid;(HO)2BDC@CrN;CO2/N2 Separation;CO2-TPD
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