Poly(ethylene glycol) 첨가에 따른 Poly(acrylamide-co-potassium methacrylate) 하이드로젤의 독성 중금속 이온에 대한 수분흡수, 자극반응 및 흡착 능력 조절

Syed Wasim Ali; Munib Ahmed Shafique; Muhammad Arif Malik; Muhammad Saad; Syeda Rida Amber; Aatiqa Jabeen

Polymer(Korea), Vol.45, No.6, 832-840, November, 2021

DOI10.7317/pk.2021.45.6.832 Export Citation

Poly(ethylene glycol) 첨가에 따른 Poly(acrylamide-co-potassium methacrylate) 하이드로젤의 독성 중금속 이온에 대한 수분흡수, 자극반응 및 흡착 능력 조절

Adjusting Water Absorption, Stimulus-Response and Adsorption Capacity for Toxic Heavy Metal Ions of Poly(acrylamide-co-potassium methacrylate) Hydrogel by Poly(ethylene glycol) Addition

Syed Wasim Ali^†, Munib Ahmed Shafique¹, Muhammad Arif Malik², Muhammad Saad, Syeda Rida Amber³, and Aatiqa Jabeen⁴

Chemistry Division, Pakistan Institute of Nuclear Science and Technology (PINSTECH), PO 45650, Nilore, Islamabad, Pakistan
¹Central Analytical Facility Division, Pakistan Institute of Nuclear Science and Technology (PINSTECH), PO 45650, Nilore, Islamabad, Pakistan
²Department of Chemistry and Biochemistry, Hampton University, Hampton, VA 23668, USA
³Chemistry Department, University of Wah, Quaid Avenue, PO 47040, Wah Cantt, Pakistan
⁴Department of Chemistry, Quaid-i-Azam University, Islamabad 45320, Pakistan

E-mail:

Hydrogels, composed of poly(acrylamide-potassium methacrylate), cross-linked with N,N'-methylene bis-acrylamide, and having different proportions of poly(ethylene glycol) were synthesized by a free radical copolymerization technique. The effect of the cross-linkage and poly(ethylene glycol) contents on swelling in water, diffusion kinetics of water in the hydrogel matrix, stimuli response to pH, ionic strength of the external solution, and capacity for chromium(III) and uranyl ions from polluted water samples were evaluated. The results show that the swelling in water decreased. Still, the diffusion rate of water in the copolymer matrix increased with an increase in the cross-linkage and an increase in the poly(ethylene glycol) amount under the conditions of this study. Poly(ethylene glycol) addition provided another tool to adjust the swelling, diffusion kinetics, and adsorption characteristics of the hydrogel. For example, poly(ethylene glycol) addition made the hydrogel adsorb uranyl ions from polluted water.

Keywords:free radical polymerization;diffusion coefficient;chromium(III);uranyl ion

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[4] Wongjaikham W, Wongsawaeng D, Hosemann P, J. Nucl. Sci. Technol., 56, 541 (2019)

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[9] Saraydin D, Isikver Y, Karadag E, Polym. Eng. Sci., 58(3), 310 (2018)

[10] Oucif A, Haddadine N, Zakia D, Bouslah N, Benaboura A, Beyaz K, Guedouar B, El-Shall MS, Polym. Bull.

[11] Yuan D, Jacquier JC, O’Riordan ED, Food Chem., 239, 1200 (2018)

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[14] Omidian H, Hashemi SA, Askari F, Nafisi S, Iranian J. Polym. Sci. Technol., 3, 115 (1994)

[15] Khare AR, Peppas NA, Biomaterials, 16, 559 (1995)

[16] Castel D, Ricard A, Audebert R, J. Appl. Polym. Sci., 39, 11 (1990)

[17] Hosseinzadeh H, Alijani D, Polym. Korea, 38(5), 588 (2014)

[18] Mahdavinia GR, Pourjavadi A, Hosseinzadeh H, Zahuriaan MJ, Eur. Polym. J., 40, 1399 (2004)

[19] Liu Y, Cao X, Hua R, Wang Y, Liu Y, Pang C, Wang Y, Hydrometallurgy, 104, 150 (2010)

[20] Ali AEH, Shawky HA, El-Rehim HAA, Hegazy EA, Eur. Polym. J., 39, 2337 (2003)

[21] Akkaya R, Ulusoy U, J. Hazard. Mater., 151(2-3), 380 (2008)

[22] Kam E, Tasdelen B, Osmanlioglu AE, Radiat. Phys. Chem., 81, 618 (2012)

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[24] Hennink WE, Van Nostrum CF, Adv. Drug. Deliv. Rev., 54, 13 (2002)

[25] Guilherme MR, Aouada FA, Fajardo AR, et al., Eur. Polym. J., 72, 365 (2015)

[26] Ricka J, Tanaka T, Macromolecules, 17, 2916 (1984)

[27] Zhou X, Weng L, Chen Q, Zhang J, Shen D, Li Z, Shao M, Xu J, Polym. Int., 52, 1153 (2003)

[28] Kiatkamjornwong S, Mongkolsawat K, Sonsuk M, Polymer, 43(14), 3915 (2002)

[29] Ion exchangers; Dorfner, K. Ed.: Walter de Gruyter: New York, 1991.