실리카 나노 충진재의 표면 처리에 따른 고분자 치아수복재의 중합 특성

김오영; Ohyoung Kim

Journal of the Korean Industrial and Engineering Chemistry, Vol.14, No.3, 313-319, May, 2003

Export Citation

실리카 나노 충진재의 표면 처리에 따른 고분자 치아수복재의 중합 특성

Polymerization Behavior of POlymeric Dental Restorative Composite Through the Surface Treatment of Silica Nanofiller

김오영 ^†

단국대학교 공과대학 공학부 고분자공학전공, 서울 140-714

Ohyoung Kim^†

Department of Polymer Science & Engineering, Dankook University, Seoul 140-714, Korea

E-mail:

초록

친수성을 띤 실리카 나노 필러 표면을 동결건조법을 사용하여 필러를 기준으로 γ-methacryloylpropyltrimethoxysilane (γ-MPS)의 농도를 각각 0, 5, 8, 10, 20 wt%까지 변화시켜 소수성으로 처리한 후 2,2'-bis-[4-(3-methacryloxy-2-hydroxypropoxy)phenyl]propane와 triethyleneglycol dimethacrylate (70/30 wt%) resin matrix와 함께 가시광선 중합형 고분자 치아수복재(polymeric dental restorative composite, PDRC)를 제조하였다. 제조된 PDRC에 의하여 γ-MPS 농도에 따른 중합 특성을 치과용 규격에 따라 중합전환률, 중합수축률, 중합깊이 등을 측정함으로써 비교하였으며 이에 따른 PDRC의 마모저항성과 표면 특성을 내마모기와 시차주사현미경을 사용하여 고찰하였다. 또한 필러 표면의 소수성 처리에 따른 필러 함량별 PDRC의 중합 특성을 표면 처리하지 않은 필러를 사용하여 제조한 대조군 PDRC와 함께 고찰한 결과, γ-MPS로 표면 처리한 필러를 사용하여 제조한 PDRC가 대조군에 비해 동일한 필러 충진량에서 제반 중합 특성이 향상됨을 알 수 있었다.

The preparation of visible light activated polymeric dental restorative composite (PDRC) was carried out using fumed silica nanofiller, of which the surface was hydrophobically treated with various concentration of γ-methacryloylpropyltrimethoxysilane (γ-MPS): 0, 5, 8, 10 and 20 wt% of nanofiller. To improve the miscibility of filler with resin matrix, which consisted of 70/30 wt% ratio of 2,2'-bis-[4-(3-methacryloxy-2-hydroxypropoxy)phenyl]propane and triethyleneglycol dimethacrylate, respectively, freeze drying method was adopted for the hydrophobic treatment of filler's surface. From the measurement of degree of conversion, polymerization shrinkage, and depth of cure, the polymerization behavior of PDRC was investigated in accordance with recommended dental specifications. Both the abrasion resistance and the surface characteristics were also investigated. Results of the polymerization behavior and scanning slectron microscopy studies showed that PDRC prepared using γ-MPS treated filler had a superior polymerization behavior and surface properties compared to those of PDRC with untreated filler.

Keywords:restorative;nanofiller;dimethacrylate;freeze drying;polymerization behavior

[References]

Philips RW, Skinner's Science of Dental Materials, 8th ed., Igaku-Shoin/Saunders, 177 (1982)
Willeam G, Lambrechts P, Bream M, Vanherle G, Quint. Int., 24(9), 641 (1993)
Kim O, J. Korean Ind. Eng. Chem., 11(6), 651 (2000)
Combe EC, Burke FJT, Douglas WH, Dental Materials, Kluwer Academic Publishers, Boston, U.S.A. (1999)
Paffenbarger GC, Rupp NW, Int. Dent. J., 24, 1 (1974)
Tylman SC, Peyton EA, Acrylics and Other Synthetic Resins in Dentistry, J.B. Lippincott Co., Philadelphia, U.S.A. (1946)
Williams DF, Materials Science and Technology, Vol. 14, VCH, Cambridge, U.K., 209 (1992)
Craig RG, Restorative Dental Materials, 8th ed., CV. Mosby, St. Louis, U.S.A., 514 (1989)
Ferraccane JL, Condon JR, Dent. Mater., 8, 290 (1992)
Luts F, Philips RW, J. Prosth. Dent., 50, 480 (1983)
Kim O, Lee T, Gong MS, J. Korean Ind. Eng. Chem., 13(3), 268 (2002)
Kim O, Lee T, J. Korean Ind. Eng. Chem., 12(1), 65 (2001)
Jang J, The Adhesion Promotion of Composite Interface and Corrosion Protection for Metal Surface by Using Silane Derivatives, Ph.D. Dissertation, Case Western Reserve University, U.S.A. (1988)
Peutzfeldt A, Eur. J. Oral Sci., 105, 97 (1997)
Chun J, Optimum Design of Polymeric Dental Restorative Material with Enhanced Volumetric Dimensional Stability, Master of Eng. Dissertation, Dankook Univ., Seoul, Korea (2002)
Kim O, Lee T, J. Ind. Eng. Chem., 7(2), 78 (2001)
Kim O, Shim WJ, Polym. Compos., 22(5), 650 (2001)
Wu WL, Fanconi BM, Polym. Eng. Sci., 23, 704 (1983)
Ferracane JL, Greener EH, J. Dent. Res., 63(8), 1093 (1984)
Counsil on Dental Materials, Instruments and Equipment, American Dental Association Specification No 27 for Resin-base Filling Materials (1993)
Cowperthwatte GF, Foy JJ, Malloy MA, Biomedical and Dental Applications of Polymers, eds. by C.G. Gebelein and F.F. Koblitz, Plenum Press, New York, 379 (1981)
Sandner B, Baudach S, Davy KWM, Braden M, Clarke RL, J. Mater. Sci. Mater. Med., 17, 39 (1997)
Davy KWM, Anseau MR, Odlyha M, Foster GM, Polym. Int., 43, 143 (1997)
Ishida H, Kumar G, Molecular Characterization of Composite Interfaces, Plenum Press, New York (1985)
Atmadja G, Bryant RW, Aust. Dent. J., 35(3), 213 (1990)
Dentistry-Resin based Filliang Materials, ISO Spec. No. 4049 (1978)
Jorgensen KD, Horsted P, Janum O, Krogh J, Schultz J, Scand. J. Dent. Res., 87, 140 (1979)
Lim BS, Ferracane JL, Condon JR, Adey JD, Dent. Mater., 18, 1 (2002)

[Referenced By]

[Related Articles]

[1] Philips RW, Skinner's Science of Dental Materials, 8th ed., Igaku-Shoin/Saunders, 177 (1982)

[2] Willeam G, Lambrechts P, Bream M, Vanherle G, Quint. Int., 24(9), 641 (1993)

[3] Kim O, J. Korean Ind. Eng. Chem., 11(6), 651 (2000)

[4] Combe EC, Burke FJT, Douglas WH, Dental Materials, Kluwer Academic Publishers, Boston, U.S.A. (1999)

[5] Paffenbarger GC, Rupp NW, Int. Dent. J., 24, 1 (1974)

[6] Tylman SC, Peyton EA, Acrylics and Other Synthetic Resins in Dentistry, J.B. Lippincott Co., Philadelphia, U.S.A. (1946)

[7] Williams DF, Materials Science and Technology, Vol. 14, VCH, Cambridge, U.K., 209 (1992)

[8] Craig RG, Restorative Dental Materials, 8th ed., CV. Mosby, St. Louis, U.S.A., 514 (1989)

[9] Ferraccane JL, Condon JR, Dent. Mater., 8, 290 (1992)

[10] Luts F, Philips RW, J. Prosth. Dent., 50, 480 (1983)

[11] Kim O, Lee T, Gong MS, J. Korean Ind. Eng. Chem., 13(3), 268 (2002)

[12] Kim O, Lee T, J. Korean Ind. Eng. Chem., 12(1), 65 (2001)

[13] Jang J, The Adhesion Promotion of Composite Interface and Corrosion Protection for Metal Surface by Using Silane Derivatives, Ph.D. Dissertation, Case Western Reserve University, U.S.A. (1988)

[14] Peutzfeldt A, Eur. J. Oral Sci., 105, 97 (1997)

[15] Chun J, Optimum Design of Polymeric Dental Restorative Material with Enhanced Volumetric Dimensional Stability, Master of Eng. Dissertation, Dankook Univ., Seoul, Korea (2002)

[16] Kim O, Lee T, J. Ind. Eng. Chem., 7(2), 78 (2001)

[17] Kim O, Shim WJ, Polym. Compos., 22(5), 650 (2001)

[18] Wu WL, Fanconi BM, Polym. Eng. Sci., 23, 704 (1983)

[19] Ferracane JL, Greener EH, J. Dent. Res., 63(8), 1093 (1984)

[20] Counsil on Dental Materials, Instruments and Equipment, American Dental Association Specification No 27 for Resin-base Filling Materials (1993)

[21] Cowperthwatte GF, Foy JJ, Malloy MA, Biomedical and Dental Applications of Polymers, eds. by C.G. Gebelein and F.F. Koblitz, Plenum Press, New York, 379 (1981)

[22] Sandner B, Baudach S, Davy KWM, Braden M, Clarke RL, J. Mater. Sci. Mater. Med., 17, 39 (1997)

[23] Davy KWM, Anseau MR, Odlyha M, Foster GM, Polym. Int., 43, 143 (1997)

[24] Ishida H, Kumar G, Molecular Characterization of Composite Interfaces, Plenum Press, New York (1985)

[25] Atmadja G, Bryant RW, Aust. Dent. J., 35(3), 213 (1990)

[26] Dentistry-Resin based Filliang Materials, ISO Spec. No. 4049 (1978)

[27] Jorgensen KD, Horsted P, Janum O, Krogh J, Schultz J, Scand. J. Dent. Res., 87, 140 (1979)

[28] Lim BS, Ferracane JL, Condon JR, Adey JD, Dent. Mater., 18, 1 (2002)