Temperature Factor in the Synthesis of Nanostructures on the Surface of Solid by the Molecular Layering Method

A. A. Malkov; A. A. Malygin; Chul-Tae Lee

Journal of Industrial and Engineering Chemistry, Vol.12, No.5, 739-744, September, 2006

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Temperature Factor in the Synthesis of Nanostructures on the Surface of Solid by the Molecular Layering Method

A. A. Malkov, A. A. Malygin^†, and Chul-Tae Lee^{1, †}

Department of Chemical Technology of Materials and Devices of Electronical Industry, St. Petersburg StateTechnological Institute (Technical University) St. Petersburg 190013, Russian Federation
¹Department of Chemical Engineering, Dankook University, Seoul 140-714, Korea

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The influence of the preliminary heat treatment temperature (Tt) of alumina and silica, the chemisorption temperature (Tch), and the desorption temperature (Tdes) in the molecular layering process on the chemical structure and phase state of the products of the chemisorption of titanium tetrachloride and the oxichlorides of vanadium and phosphorus are presented in this paper. It is shown that with the increase of Tt, the number of bonds and the concentration of forming element-chloride groups with surface decreases; with the increase of Tch from 200 to 800 ℃, the number of bonds of forming element-chloride groups with surface increases while titanium concentration in chemisoption products decreases. On the surface of silica at Tch below of 350 ℃, the mono-phase structure was formed with adequate anatase modification of TiO2. At Tch ≥ 350 ℃, bi-phase was formed with adequate anatase and rutile. On the surface of alumina, in contrast, a bi-phase structure was formed at low temperature. With the increase of Tch, the part of the anatase form of TiO2 grew, up to 100 % at 600 ℃ .

Keywords:molecular layering method;synthesis;nanostructure;nanocomposition

[References]

Malygin AA, J. Ind. Eng. Chem., 12(1), 1 (2006)
Koltzov SI, Aleskovskii VB, in Abstracts of Sci.-Tech. Conf., Goskhimizdat, Leningrad, 37 (1963)
Koltzov SI, Aleskovskii VB, Zh. Fizch. Zh. Fizch., 42, 1210 (1968)
Aleskovskii VB, Stoichiometry and Synthesis of Solid Compounds, Nauka, Leningrad, 1976 (in Russian)
Aleskovskii VB, Zh. Prikl. Khim., 47, 102145 (1974)
Malygin AA, Malkov AA, Dubrovenskii SD, In Adsorption on New and Modified InorganicSorbents. A. Dabrowski and V. A. Tertykh, Eds. In serie “Studies in Surface Science and Catalysis”. Amsterdam, Netherlands: Elsevier, 99, 213 (1996)
Aleskovskii VB, Chemistry of Solid Substances (in Russian), Vyschaya Shcola, Moskow (1978)
Malygin AA, The molecular layering method as a basis of chemical nanotechnology. In Book: Natural Microporous Materials in Environmental Technology. :Kluwer Academic Publishers, 487 (1999)
Kim HB, Lee CH, Choi JS, Park BJ, Lim ST, Choi HJ, J. Ind. Eng. Chem., 11(5), 769 (2005)
Trifonov SA, Sosnov EA, Malygin AA, J. Appl. Chem., 77, 1872 (2004)
Ishutina ZN, Gusarov VV, Malkov VV, Firsanova TV, Malygin AA, J. Inorg. Chem., 44, 16 (1999)
Malkov VV, Sosnov EA, Malygin AA, J. Appl. Chem., 78, 881 (2005)
Gun'ko VM, Leboda R, Marciniak M, Grzegorczyk W, Skubiszewska-Zieba J, Malygin AA, Malkov AA, Langmuir, 16(7), 3227 (2000)
Leboda R, Turov VV, Marciniak M, Malygin AA, Malkov AA, Langmuir, 15(24), 8441 (1999)
Aleskovskii VB, Chemistry of nadmolekulasolid substances (in Russian), Saint-Petersburg, SPU, 256 (1996)
Sosnov SA, Malkov AA, Malygin AA, Zh. Prikl. Khim., 73, 1074 (2000)
Malygin AA, Malkov AA, Industry and Education. M. (inRussian), MSTU, N 2.- 48 (2002)
Malkov AA, Sosnov SA, Malygin AA, Zh. Prikl. Khim. (russian ed.), 77, 1245 (2004)
Koltzov SI, Malygin AA, Volkova AN, Aleskovskiy VB, J. Phis. Chem. (in Russian ed.), N4, 988 (1973)
Malkov AA, Sosnov SA, Malygin AA, in Napravlenniy sintez tverdykhveschestv (in Russian), Issue 3. Ed. by V. B. Aleskovskiy, St. Petersburg, USSR, 29 (1993)
Petrova LI, Malkov AA, Malygin AA, Zh. Prikl. Khim., 64, 763 (1991)
Sosnov SA, Malkov AA, Malygin AA, Zh, Prikl. Khim., 61, 29 (1988)
Zhaobin W, Qin X, Xiexian G, Appl. Catal., 63, 305 (1990)
Damyanov D, Vlaev L, Bull. Chem. Soc. Jpn., 56, 1841 (1989)
Melchor A, Garbowski E, Mathieu MV, Primet M, J. Chem. Soc.-Faraday Trans., 82, 1899 (1986)
Petrova LI, Malkov AA, Malygin AA, Zh. Prikl. Khim., 59, 2277 (1986)
Foger K, Anderson JR, Appl. Catal., 23, 139 (1986)
Kytokivi A, Lindblad M, Root A, J. Chem. Soc. Faraday Trans., 91, 941 (1995)
Malkov AA, Sosnov SA, Osipenkova OB, Malygin AA, Appl. Surf. Sci., 108, 133 (1997)
Malygin AA, Khimicheskaya sborka materialov szadannymi svoystvami Studeny course of Leningrad technological institue (in Russian), Leningrad, USSR (1986)
Koltzov SI, Kopylov VB, Smirnov VM, Aleskovskii VB, Zh. Prikl. Khim, 49, 516 (1976)
Osipenkova OV, Malkov AA, Malygin AA, Zh. Obshch. Khim., N4, 549 (1994)

[Related Articles]

[1] Malygin AA, J. Ind. Eng. Chem., 12(1), 1 (2006)

[2] Koltzov SI, Aleskovskii VB, in Abstracts of Sci.-Tech. Conf., Goskhimizdat, Leningrad, 37 (1963)

[3] Koltzov SI, Aleskovskii VB, Zh. Fizch. Zh. Fizch., 42, 1210 (1968)

[4] Aleskovskii VB, Stoichiometry and Synthesis of Solid Compounds, Nauka, Leningrad, 1976 (in Russian)

[5] Aleskovskii VB, Zh. Prikl. Khim., 47, 102145 (1974)

[6] Malygin AA, Malkov AA, Dubrovenskii SD, In Adsorption on New and Modified InorganicSorbents. A. Dabrowski and V. A. Tertykh, Eds. In serie “Studies in Surface Science and Catalysis”. Amsterdam, Netherlands: Elsevier, 99, 213 (1996)

[7] Aleskovskii VB, Chemistry of Solid Substances (in Russian), Vyschaya Shcola, Moskow (1978)

[8] Malygin AA, The molecular layering method as a basis of chemical nanotechnology. In Book: Natural Microporous Materials in Environmental Technology. :Kluwer Academic Publishers, 487 (1999)

[9] Kim HB, Lee CH, Choi JS, Park BJ, Lim ST, Choi HJ, J. Ind. Eng. Chem., 11(5), 769 (2005)

[10] Trifonov SA, Sosnov EA, Malygin AA, J. Appl. Chem., 77, 1872 (2004)

[11] Ishutina ZN, Gusarov VV, Malkov VV, Firsanova TV, Malygin AA, J. Inorg. Chem., 44, 16 (1999)

[12] Malkov VV, Sosnov EA, Malygin AA, J. Appl. Chem., 78, 881 (2005)

[13] Gun'ko VM, Leboda R, Marciniak M, Grzegorczyk W, Skubiszewska-Zieba J, Malygin AA, Malkov AA, Langmuir, 16(7), 3227 (2000)

[14] Leboda R, Turov VV, Marciniak M, Malygin AA, Malkov AA, Langmuir, 15(24), 8441 (1999)

[15] Aleskovskii VB, Chemistry of nadmolekulasolid substances (in Russian), Saint-Petersburg, SPU, 256 (1996)

[16] Sosnov SA, Malkov AA, Malygin AA, Zh. Prikl. Khim., 73, 1074 (2000)

[17] Malygin AA, Malkov AA, Industry and Education. M. (inRussian), MSTU, N 2.- 48 (2002)

[18] Malkov AA, Sosnov SA, Malygin AA, Zh. Prikl. Khim. (russian ed.), 77, 1245 (2004)

[19] Koltzov SI, Malygin AA, Volkova AN, Aleskovskiy VB, J. Phis. Chem. (in Russian ed.), N4, 988 (1973)

[20] Malkov AA, Sosnov SA, Malygin AA, in Napravlenniy sintez tverdykhveschestv (in Russian), Issue 3. Ed. by V. B. Aleskovskiy, St. Petersburg, USSR, 29 (1993)

[21] Petrova LI, Malkov AA, Malygin AA, Zh. Prikl. Khim., 64, 763 (1991)

[22] Sosnov SA, Malkov AA, Malygin AA, Zh, Prikl. Khim., 61, 29 (1988)

[23] Zhaobin W, Qin X, Xiexian G, Appl. Catal., 63, 305 (1990)

[24] Damyanov D, Vlaev L, Bull. Chem. Soc. Jpn., 56, 1841 (1989)

[25] Melchor A, Garbowski E, Mathieu MV, Primet M, J. Chem. Soc.-Faraday Trans., 82, 1899 (1986)

[26] Petrova LI, Malkov AA, Malygin AA, Zh. Prikl. Khim., 59, 2277 (1986)

[27] Foger K, Anderson JR, Appl. Catal., 23, 139 (1986)

[28] Kytokivi A, Lindblad M, Root A, J. Chem. Soc. Faraday Trans., 91, 941 (1995)

[29] Malkov AA, Sosnov SA, Osipenkova OB, Malygin AA, Appl. Surf. Sci., 108, 133 (1997)

[30] Malygin AA, Khimicheskaya sborka materialov szadannymi svoystvami Studeny course of Leningrad technological institue (in Russian), Leningrad, USSR (1986)

[31] Koltzov SI, Kopylov VB, Smirnov VM, Aleskovskii VB, Zh. Prikl. Khim, 49, 516 (1976)

[32] Osipenkova OV, Malkov AA, Malygin AA, Zh. Obshch. Khim., N4, 549 (1994)