Chemical absorption of carbon dioxide into oxirane solution containing ID-CP-MS41 catalyst

Kwang-Joong Oh; Seong-Man Mun; Seong-Soo Kim; Sang-Wook Park

Korean Journal of Chemical Engineering, Vol.28, No.2, 567-574, February, 2011

DOI10.1007/s11814-010-0388-z Export Citation

Chemical absorption of carbon dioxide into oxirane solution containing ID-CP-MS41 catalyst

Kwang-Joong Oh, Seong-Man Mun, Seong-Soo Kim¹, and Sang-Wook Park^{2, †}

School of Civil and Environmental Engineering, Pusan National University, Busan 609-735, Korea
¹Department of Environmental Administration, Catholic University of Pusan, Busan 609-757, Korea
²School of Chemical and Biomolecular Engineering, Pusan National University, Busan 609-735, Korea

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CP-MS41 was synthesized by hydrolysis of tetraorthosilicate, as a silicon source, with 3-chloropropyltriethoxysilane as an organosilane using cetyltrimethylammonium bromide as a template. ID-CP-MS41 was synthesized by immobilization of imidazole on the CP-MS41 and was dispersed in organic liquid as a mesoporous catalyst for the reaction between carbon dioxide and oxirane. Phenyl glycidyl ether and glycidyl methacrylate were used as oxiranes. Carbon dioxide was absorbed into the oxirane solution in a stirred batch tank with a planar gas-liquid interface within a range of 0-2.0 kmol/m3 of oxirane and 333-363 K at 101.3 kPa. The measured values of absorption rate were analyzed to obtain the reaction kinetics using the mass transfer mechanism associated with the chemical reactions based on the film theory. The overall reaction of CO2 with oxirane, which is assumed to consist of two steps--i) a reversible reaction between oxirane (B) and catalyst of ID-CP-MS41 (QX) to form an intermediate complex (C1), and ii) irreversible reaction between C1 and CO2 to form QX and five-membered cyclic carbonate (C)--was used to obtain the reaction kinetics through the pseudo-first-order reaction model. Polar solvents such as N, N-dimethylacetamide, Nmethyl-2-pyrrolidinone, and dimethyl sulfoxide affected the reaction rate constants.

Keywords:Absorption;Carbon Dioxide;Oxirane;Imidazole;MCM-41

[References]

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Peppel WJ, Ind. Eng. Chem., 50, 767 (1950)
Rokicki G, Makromol.Chem., 186, 331 (1985)
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Nishikubo Y, Kato T, Sugimoto S, Tomoi M, Ishigaki S, Macromolecules., 23, 3406 (1990)
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Daraiswany LK, Sharma MM, Heterogeneous reaction: Analysis, example and reactor design., John Wiley & Sons, New York (1980)
Park SW, Park DW, Kim TY, Park MY, Oh KJ, Catal. Today, 98(4), 493 (2004)
Park SW, Park DW, Lee JW, Korean J. Chem. Eng., 23(4), 645 (2006)
Park SW, Choi BS, Lee BD, Park DW, Kim SS, Sep. Sci. Technol., 41(5), 829 (2006)
Son YS, Park SW, Park DW, Oh KJ, Kim SS, Korean J. Chem. Eng., 26(5), 1359 (2009)
Park SW, Choi BS, Park DW, Kim SS, Lee JW, Korean J. Chem. Eng., 24(6), 953 (2007)
Park SW, Choi BS, Park DW, Oh KJ, Lee JW, Green Chem., 9, 605 (2007)
Son YS, Park SW, Park DW, Oh KJ, Kim SS, Korean J. Chem. Eng., 26(3), 783 (2009)
Kresge CT, Leonowicz ME, Roth WJ, Vartuli JC, Beck JS, Nature., 359, 710 (1992)
Beck JS, Vartuli JC, Roth WJ, Leonowicz ME, Kresge CT, Schmitt KD, Chu CTW, Olson DH, Sheppard EW, McCullen SB, Higgins JB, Schlenker JL, J. Am. Chem. Soc., 114, 10834 (1992)
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Xu S, Huang C, Zhang J, Liu J, Chen B, Korean J. Chem. Eng., 26(4), 985 (2009)
Udayakumar S, Park SW, Park DW, Choi BS, Catal. Commun., 9, 1563 (2008)
Park SW, Park DW, Oh KJ, Kim SS, Sep. Sci., Technol., 41, 543 (2009)
Kennard ML, Meisen A, J. Chem. Eng. Data., 29, 309 (1984)
Reid RC, Prausnitz JM, Sherwwod TK, The properties of gases and liquids., McGraw-Hill, New York (1977)
Cussler EL, Diffusion., Cambridge University Press, New York (1984)
Carta G, Pigford RL, Ind. Eng. Chem. Fundam., 22, 329 (1983)
Herbrandson HF, Neufeld FB, J. Org. Chem., 31, 1140 (1966)
Brandrup J, Immergut EH, Polymer Handbook., Second Ed., John Wiley & Sons, New York (1975)
Morrison RT, Boyd RN, Organic Chemistry., Fourth Ed., Allyn and Bacon, Inc., Toronto (1983)

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[1] Aresta M, Carbon dioxide recovery and utilization., Kluwer Academic Publishers, London (2003)

[2] Weissermel K, Arpe H, Industrial organic chemistry., Wiley-VCH, Weinheim, New York (1997)

[3] Peppel WJ, Ind. Eng. Chem., 50, 767 (1950)

[4] Rokicki G, Makromol.Chem., 186, 331 (1985)

[5] Aida T, Inoue S, J. Am. Chem. Soc., 105, 1304 (1983)

[6] Nishikubo Y, Kato T, Sugimoto S, Tomoi M, Ishigaki S, Macromolecules., 23, 3406 (1990)

[7] Kihara N, Endo T, Macromolecules., 25, 4824 (1992)

[8] Nishikubo T, Kameyama A, Yamashida J, Tomoi M, Fukuda W, J. Polym. Sci., Part A, Polym. Chem., 31, 939 (1993)

[9] Nishikubo T, Kameyama A, Yamashita J, Fukumitsu T, Maejima C, Tomoi M, J. Polym. Sci. A: Polym. Chem., 33(7), 1011 (1995)

[10] Starks CM, Liotta CL, Halpern M, Phase transfer catalysis., Chapman & Hall, New York (1994)

[11] Daraiswany LK, Sharma MM, Heterogeneous reaction: Analysis, example and reactor design., John Wiley & Sons, New York (1980)

[12] Park SW, Park DW, Kim TY, Park MY, Oh KJ, Catal. Today, 98(4), 493 (2004)

[13] Park SW, Park DW, Lee JW, Korean J. Chem. Eng., 23(4), 645 (2006)

[14] Park SW, Choi BS, Lee BD, Park DW, Kim SS, Sep. Sci. Technol., 41(5), 829 (2006)

[15] Son YS, Park SW, Park DW, Oh KJ, Kim SS, Korean J. Chem. Eng., 26(5), 1359 (2009)

[16] Park SW, Choi BS, Park DW, Kim SS, Lee JW, Korean J. Chem. Eng., 24(6), 953 (2007)

[17] Park SW, Choi BS, Park DW, Oh KJ, Lee JW, Green Chem., 9, 605 (2007)

[18] Son YS, Park SW, Park DW, Oh KJ, Kim SS, Korean J. Chem. Eng., 26(3), 783 (2009)

[19] Kresge CT, Leonowicz ME, Roth WJ, Vartuli JC, Beck JS, Nature., 359, 710 (1992)

[20] Beck JS, Vartuli JC, Roth WJ, Leonowicz ME, Kresge CT, Schmitt KD, Chu CTW, Olson DH, Sheppard EW, McCullen SB, Higgins JB, Schlenker JL, J. Am. Chem. Soc., 114, 10834 (1992)

[21] Bhaumik A, Tatsumi T, J. Catal., 189(1), 31 (2000)

[22] Xu S, Huang C, Zhang J, Liu J, Chen B, Korean J. Chem. Eng., 26(4), 985 (2009)

[23] Udayakumar S, Park SW, Park DW, Choi BS, Catal. Commun., 9, 1563 (2008)

[24] Park SW, Park DW, Oh KJ, Kim SS, Sep. Sci., Technol., 41, 543 (2009)

[25] Kennard ML, Meisen A, J. Chem. Eng. Data., 29, 309 (1984)

[26] Reid RC, Prausnitz JM, Sherwwod TK, The properties of gases and liquids., McGraw-Hill, New York (1977)

[27] Cussler EL, Diffusion., Cambridge University Press, New York (1984)

[28] Carta G, Pigford RL, Ind. Eng. Chem. Fundam., 22, 329 (1983)

[29] Herbrandson HF, Neufeld FB, J. Org. Chem., 31, 1140 (1966)

[30] Brandrup J, Immergut EH, Polymer Handbook., Second Ed., John Wiley & Sons, New York (1975)

[31] Morrison RT, Boyd RN, Organic Chemistry., Fourth Ed., Allyn and Bacon, Inc., Toronto (1983)