화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.18, No.3, 1096-1101, May, 2012
DOI10.1016/j.jiec.2011.12.011  Export Citation
Oxidative dehydrogenation of n-butane to n-butene and 1,3-butadiene over Mg3(VO4)2/MgO-ZrO2 catalysts: Effect of Mg:Zr ratio of support
Jong Kwon Lee, Howon Lee, Ung Gi Hong, Jinsuk Lee1, Young-Jin Cho1, Yeonshick Yoo1, Ho-Sik Jang1, and In Kyu Song†
  • School of Chemical and Biological Engineering, Institute of Chemical Processes, Seoul National University, Shinlim-dong, Kwanak-ku, Seoul 151-744, South Korea
  • 1Samsung Total Petrochemicals Corporation, Daesan 356-711, South Korea
E-mail:
MgO-ZrO2 supports with different Mg:Zr ratios (16:1, 8:1, 4:1, 2:1, and 1:1) were prepared by a geloxalate co-precipitation method, and Mg3(VO4)2/MgO.ZrO2 catalysts were then prepared by a wet impregnation method. The prepared catalysts were applied to the oxidative dehydrogenation of n-butane to n-butene and 1,3-butadiene. Experimental results revealed that oxygen capacity and acidity of the catalyst were closely related to the catalytic performance. Among the catalyst tested, Mg3(VO4)2/MgO-ZrO2 (4:1) catalyst, which retained the largest oxygen capacity and acidity, exhibited the best catalytic performance in the oxidative dehydrogenation of n-butane.
Keywords:Oxidative dehydrogenation;n-Butane;Oxygen capacity;Acidity;Vanadium-magnesium oxide
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