화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.36, 314-319, April, 2016
DOI10.1016/j.jiec.2016.02.021  Export Citation
Removal of copper(II) in aqueous solution using pyrolytic biochars derived from red macroalga Porphyra tenera
Sung Hoon Park, Hye Jung Cho1, Changkook Ryu2, and Young-Kwon Park1, †
  • Department of Environmental Engineering, Sunchon National University, Suncheon 57922, Republic of Korea
  • 1School of Environmental Engineering, University of Seoul, Seoul 02504, Republic of Korea
  • 2School of Mechanical Engineering, Sungkyunkwan University, Suwon 16419, Republic of Korea
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Steam activation enhanced the copper removal performance of Porphyra tenera-derived biochar significantly by increasing the quantity of exchangeable cations, whereas KOH activation reduced the copper removal performance of the biochar, despite the huge increase in specific surface area and pore volume, by washing out the exchangeable cations into the basic KOH solution. Both ion exchange and adsorption appeared to be important mechanisms for copper removal by P. tenera-derived biochar but ion exchange may be a more important mechanism. The pseudo-2nd order kinetic model and the Langmuir's isotherm model provided a good interpretation of the kinetics and equilibrium of copper removal.
Keywords:Macroalga;Porphyra tenera;Adsorption;Copper;Biochar
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