화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.45, 111-120, January, 2017
DOI10.1016/j.jiec.2016.09.013  Export Citation
Composition effect of metal species in (Ni, Fe, Co)-Bi-O/gamma-Al2O3 catalyst on oxidative dehydrogenation of n-butane to butadiene
G. Tanimu1, B.R. Jermy2, S. Asaoka2, and S. Al-Khattaf2, 1, †
  • 1Department of Chemical Engineering, King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi Arabia
  • 2Center of Research Excellence in Petroleum Refining and Petrochemicals, King Fahd University of Petroleum & Minerals, Dhahran 31261, Saudi Arabia
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The effect of metal oxide species in (Ni, Fe and/or Co) oxide-Bi2O3 over gamma-alumina support was investigated for n-butane oxidative dehydrogenation. Partial substitution of Ni up to 50% by Fe improved butadiene selectivity while same substitution with Co increased n-butane conversion. The ternary Ni-Fe-Co system (10 wt% Ni-5 wt% Fe-5 wt% Co-30 wt% Bi-O/gamma-Al2O3) showed the highest butadiene selectivity of 46.3% at n-butane conversion of 30%. The acid-base sites preferably adjusted by ternary main metal combination in hierarchical cohabitation of metal (Ni, Fe and Co) oxide, Bi2O3 and gamma-Al2O3 cooperate to accelerate butadiene selectivity at both 1st and 2nd step dehydrogenations due to an increased H2 abstraction and 1-butene intermediate adsorption.
Keywords:Oxidative dehydrogenation;n-Butane;Butadiene;Nano-particle;Ternary oxide;Supported oxide
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