화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.56, 120-128, December, 2017
DOI10.1016/j.jiec.2017.07.004  Export Citation
The effect of interaction between La2AlCoO6 and CuCl2 on ethane oxychlorination
Lirong Yang, Ruisheng Hu†, Huan Li, Yun Jia, Qihua Zhou, and Hongye Wang
  • School of Chemistry and Chemical Engineering, Key Laboratory of Rare Earth Materials Chemistry and Physics, Inner Mongolia University, Hohhot 010021, PR China
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Supported perovskite-type catalyst La2AlCoO6-CuCl2-γ-Al2O3 was synthesized by impregnation-sol-gel-mechanical-mixing methods and characterized by means of XRD, BET, H2-TPR, XPS, O2-TPD and TGDSC techniques. It is found that there is a strong interaction between La2AlCoO6 and CuCl2. The catalyst La2AlCoO6-CuCl2-γ-Al2O3 reduces the reduction activation energy of Cu2+ → Cu+ and increases the amount of surface adsorbed oxygen species, which are advantageous to the transition of redox group Cu 2+/Cu+, therefore promote the catalytic performance. The catalyst La2AlCoO6-CuCl2-g-Al2O3 shows a superior catalytic activity for ethane oxychlorination with the C2H6 conversion of 100% and the C2H3Cl selectivity to 43.8%.
Keywords:Double perovskite;Copper chloride;Complex oxide;Ethane oxychlorination
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