화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.80, 392-400, December, 2019
DOI10.1016/j.jiec.2019.08.019  Export Citation
Hydrodeoxygenation of raw bio-oil towards platform chemicals over FeMoP/zeolite catalysts
Idoia Hita1, 2, †, Tomás Cordero-Lanzac1, Giuseppe Bonura3, †, Catia Cannilla3, José M. Arandes1, Francesco Frusteri3, and Javier Bilbao1
  • 1Department of Chemical Engineering, University of the Basque Country (UPV/EHU), PO Box 644-48080, Bilbao, Spain
  • 2Multiscale Reaction Engineering, KAUST Catalysis Center (KCC), King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900, Saudi Arabia
  • 3CNR-ITAE, Istituto di Tecnologie Avanzate per l'Energia “Nicola Giordano”, Via S. Lucia sopra Contesse, 5-98126 Messina, Italy
E-mail:,
The hydrodeoxygenation of raw bio-oil was investigated in a continuous fixed bed reactor over a series of FeMoP/zeolite catalysts, pursuing a maximized and stable production of phenolics and aromatics. After 5 h of reaction, the catalysts reach a pseudosteady activity state. The FeMoP/HZSM-5 catalyst yields the highest amount of carbon products (53.5 wt%) with the highest selectivity towards aromatics (13.6 wt%, dry basis) and phenolics (12.2 wt%), due to the synergy between the weak acidity of the FeMoP and the mild acidity of the HZSM-5 zeolite, which minimizes dehydration and gasification. The MFI framework allows the sweeping of coke precursors.
Keywords:Hydrodeoxygenation;Bio-oil;Aromatics;Phenolics;Deactivation;HZSM-5 zeolite
  1. Corma A, Iborra S, Velty A, Chem. Rev., 2411 (2007).
  2. Lee O, Seong DH, Lee CG, Lee EY, J. Ind. Eng. Chem., 29, 24 (2015)
  3. Si Z, Zhang X, Wang C, Ma L, Dong R, Catalysts, 7(6), 169 (2017)
  4. Lazzari E, Schena T, Marcelo MCA, Primaz CT, Silva AN, Ferrao MF, Bjerk T, Caramao EB, Ind. Crop. Prod., 111, 856 (2018)
  5. Gollakota ARK, Reddy M, Subramanyam MD, Kishore N, Renew. Sust. Energ. Rev., 58, 1543 (2016)
  6. Wildschut J, Mahfud FH, Venderbosch RH, Heeres HJ, Ind. Eng. Chem. Res., 48(23), 10324 (2009)
  7. Ma Z, Wei L, Zhou W, Jia L, Hou B, Li D, Zhao YQ, Fuel, 92(4), 855 (2018)
  8. Mullen CA, Boateng AA, Fuel, 245, 360 (2019)
  9. Cordero-Lanzac T, Palos R, Hita I, Arandes JM, Rodriguez-Mirasol J, Cordero T, Bilbao J, Castano P, Appl. Catal. B: Environ., 239, 513 (2018)
  10. Hita I, Deuss PJ, Bonura G, Frusteri F, Heeres HJ, Fuel Process. Technol., 179, 143 (2018)
  11. Lup ANK, Abnisa F, Daud WMAW, Aroua MK, J. Ind. Eng. Chem., 56, 1 (2017)
  12. He JY, Zhao C, Lercher JA, J. Catal., 309, 362 (2014)
  13. Lee EH, Park RS, Kim H, Park SH, Jung SC, Jeon JK, Kim SC, Park YK, J. Ind. Eng. Chem., 37, 18 (2016)
  14. Kim IH, Dwiatmoko AA, Choi JW, Suh DJ, Jae JH, Ha JM, Kim JK, J. Ind. Eng. Chem., 56, 74 (2017)
  15. Sapunov VN, Stepacheva AA, Sulman EM, Warna J, Maki-Arvela P, Sulman MG, Sidorov AI, Stein BD, Murzin DY, Matveeva VG, J. Ind. Eng. Chem., 46, 426 (2017)
  16. Roldugina EA, Naranov ER, Maximov AL, Karakhanov EA, Appl. Catal. A: Gen., 553, 24 (2018)
  17. Zhang XH, Tang WW, Zhang Q, Li YP, Chen LG, Xu Y, Wang CG, Ma LL, Fuel, 215, 825 (2018)
  18. Ardiyanti AR, Khromova SA, Venderbosch RH, Yakovlev VA, Heeres HJ, Appl. Catal. B: Environ., 117-118, 105 (2012)
  19. Yoosuk B, Tumnantong D, Prasassarakich P, Fuel, 91(1), 246 (2012)
  20. Zhang XH, Wang TJ, Ma LL, Zhang Q, Jiang T, Bioresour. Technol., 127, 306 (2013)
  21. Zhang XH, Chen LG, Kong W, Wang TJ, Zhang Q, Long JX, Xu Y, Ma LL, Energy, 84, 83 (2015)
  22. Zhang XH, Zhang Q, Wang TJ, Li BS, Xu Y, Ma LL, Fuel, 179, 312 (2016)
  23. Nie L, De Souza PM, Noronha FB, An W, Sooknoi T, Resasco DE, J. Mol. Catal. A-Chem., 388-389, 47 (2014)
  24. Pan Z, Wang R, Li M, Chu Y, Chen J, J. Energy Chem., 24(1), 77 (2015)
  25. Li KL, Wang RJ, Chen JX, Energy Fuels, 25(3), 854 (2011)
  26. Echeandia S, Pawelec B, Barrio VL, Arias PL, Cambra JF, Loricera CV, Fierro JLG, Fuel, 117, 1061 (2014)
  27. Shafaghat H, Rezaei PS, Daud WMAW, J. Ind. Eng. Chem., 35, 268 (2016)
  28. Rensel DJ, Kim J, Bonita Y, Hicks JC, Appl. Catal. A: Gen., 524, 85 (2016)
  29. Rensel DJ, Rouvimov S, Gin ME, Hicks JC, J. Catal., 305, 256 (2013)
  30. Rensel DJ, Kim J, Jain V, Bonita Y, Rai N, Hicks JC, Catal. Sci. Technol., 7, 1857 (2017)
  31. Jain V, Bonita Y, Brown A, Taconi A, Hicks JC, Rai N, Catal. Sci. Technol., 8, 4083 (2018)
  32. Fernandez-Akarregi AR, Makibar J, Lopez G, Amutio M, Olazar M, Fuel Process. Technol., 112, 48 (2013)
  33. Scholze B, Meier D, J. Anal. Appl. Pyrolysis, 60, 41 (2001)
  34. Cordero-Lanzac T, Palos R, Arandes JM, Castano P, Rodriguez-Mirasol J, Cordero T, Bilbao J, Appl. Catal. B: Environ., 203, 389 (2017)
  35. Valle B, Castano P, Olazar M, Bilbao J, Gayubo AG, J. Catal., 285(1), 304 (2012)
  36. Hita I, Gutierrez A, Olazar M, Bilbao J, Arandes JM, Castano P, Fuel, 145, 158 (2015)
  37. van Herk D, Castano P, Quaglia M, Kreutzer MT, Makkee M, Moulijn JA, Appl. Catal. A: Gen., 365(1), 110 (2009)
  38. Castano P, Elordi G, Olazar M, Aguayo AT, Pawelec B, Bilbao J, Appl. Catal. B: Environ., 104(1-2), 91 (2011)
  39. Al-Dughaither AS, de Lasa H, Ind. Eng. Chem. Res., 53(40), 15303 (2014)
  40. Fan Y, Cai Y, Li X, Yin H, Xia J, J. Ind. Eng. Chem., 46, 139 (2017)
  41. Xu XW, Jiang EC, Li ZY, Sun Y, Fuel, 221, 440 (2018)
  42. Ibarra A, Hita I, Azkoiti MJ, Arandes JM, Bilbao J, J. Ind. Eng. Chem., 78, 372 (2019)
  43. Zacher AH, Elliott DC, Olarte MV, Wang HM, Jones SB, Meyer PA, Biomass Bioenerg., 125, 151 (2019)
  44. Castano P, Elordi G, Ibanez M, Olazar M, Bilbao J, Catal. Sci. Technol., 2(3), 504 (2012)
  45. Kumar P, Yenumala SR, Maity SK, Shee D, Appl. Catal. A: Gen., 471, 28 (2014)
  46. Valle B, Gayubo AG, Alonso A, Aguayo AT, Bilbao J, Appl. Catal. B: Environ., 100(1-2), 318 (2010)
  47. Valle B, Gayubo AG, Aguayo AT, Olazar M, Bilbao J, Energy Fuels, 24(3), 2060 (2010)
  48. Paysepar H, Rao KTV, Yuan ZS, Shui HF, Xu CB, Appl. Catal. A: Gen., 563, 154 (2018)
  49. Dai GX, Wang SR, Zou Q, Huang SQ, Fuel Process. Technol., 179, 319 (2018)
  50. Xing J, Song L, Zhang C, Zhou MD, Yue L, Li XB, Catal. Today, 258, 90 (2015)
  51. Guisnet M, Magnoux P, Appl. Catal. A: Gen., 212(1-2), 83 (2001)
  52. Bartholomew CH, Appl. Catal. A: Gen., 212(1-2), 17 (2001)
  53. Cordero-Lanzac T, Hita I, Veloso A, Arandes JM, Rodriguez-Mirasol J, Bilbao J, Cordero T, Castano P, Chem. Eng. J., 337, 454 (2017)
  54. Elordi G, Olazar M, Lopez G, Castano P, Bilbao J, Appl. Catal. B: Environ., 102(1-2), 224 (2011)
  55. Ibanez M, Valle B, Bilbao J, Gayubo AG, Castano P, Catal. Today, 195(1), 106 (2012)
  56. Marafit M, Furimsky E, Energy Fuels, 31(6), 5711 (2017)
  57. Regali F, Liotta LF, Venezia AM, Montes V, Boutonnet M, Jaras S, Catal. Today, 223, 87 (2014)
  58. Cordero-Lanzac T, Ateka A, Perez-Uriarte P, Castano P, Aguayo AT, Bilbao J, Ind. Eng. Chem. Res., 57(41), 13689 (2018)
  59. Nikulshin PA, Sal’nikov VA, Zhilkina EO, Pimerzin AA, Catal. Ind., 6(4), 338 (2014)