Functionalized phosphorene/polypyrrole hybrid nanomaterial by covalent bonding and its supercapacitor application

Yun Ki Kim; Keun-Young Shin

Journal of Industrial and Engineering Chemistry, Vol.94, 122-126, February, 2021

DOI10.1016/j.jiec.2020.10.044 Export Citation

Functionalized phosphorene/polypyrrole hybrid nanomaterial by covalent bonding and its supercapacitor application

Yun Ki Kim, and Keun-Young Shin^{1, †}

School of Chemical and Biological Engineering, College of Engineering, Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul 08826, Republic of Korea
¹Department of Organic Materials and Fiber Engineering, Soongsil University, 369, Sangdo-ro, Dongjak-gu, Seoul 06978, Republic of Korea

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A functionalized phosphorene/polypyrrole (FPPY) hybrid nanomaterial was prepared via a mechanochemical process and chemical oxidative polymerization. The polymerization of polypyrrole (PPY) on the surface of two-dimensional phosphorene was investigated in detail. The amide bond formation of the FPPY hybrid improved the interfacial interaction between the PPY and phosphorene. The specific capacitance of the FPPY was 411.5 F g-1, which was approximately four times that of pristine PPY (106 F g-1). Additionally, hybridization improved the structural stability of PPY, yielding a cycle stability 2 times higher than that of pristine PPY. To the best of our knowledge, this is the first report on the potential of phosphorene hybridized with conducting polymers for practical energy-storage applications.

Keywords:Phosphorene;Polypyrrole;Urea;Supercapacitor

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[Referenced By]

[1] Gopalakrishnan A, Badhulika S, J. Ind. Eng. Chem., 68, 257 (2018)

[2] Bresser D, Buchholz D, Moretti A, Varzi A, Passerini S, Energy Environ. Sci., 11, 3096 (2018)

[3] Du J, Liu L, Yu Y, Zhang Y, Chen A, J. Ind. Eng. Chem., 76, 450 (2019)

[4] Wu S, Hui KS, Hui KN, Adv. Sci., 5, 170049 (2018)

[5] Pang J, Bachmatiuk A, Yin Y, Trzebicka B, Zhao L, Fu L, Mendes RG, Gemming T, Liu Z, Rummeli HM, Adv. Eng. Mater., 8, 170209 (2018)

[6] Ren XL, Lian PC, Xie DL, Yang Y, Mei Y, Huang XR, Wang ZR, Yin XT, J. Mater. Sci., 52(17), 10364 (2017)

[7] Kang J, Wood JD, Wells SA, Lee JH, Liu X, Chen KS, Hersam MC, ACS Nano, 9, 3596 (2015)

[8] Xu JY, Gao LF, Hu CX, Zhu ZY, Zhao M, Wang Q, Zhang HL, Chem. Commun., 52, 8107 (2016)

[9] Woomer AH, Farnsworth TW, Hu J, Wells RA, Donley CL, Warren SC, ACS Nano, 9, 8869 (2015)

[10] Yang ZB, Hao JH, Yuan SG, Lin SH, Yau HM, Dai JY, Lau SP, Adv. Mater., 27(25), 3748 (2015)

[11] Zhou F, Ouyang L, Zeng M, Liu J, Wang H, Shao H, Zhu M, J. Alloy. Compd., 784, 339 (2019)

[12] Ansari SA, Ansari MS, Cho MH, Phys. Chem. Chem. Phys., 18, 3921 (2016)

[13] Kim YK, Lee YR, Shin KY, J. Ind. Eng. Chem., 90, 333 (2020)

[14] Kim W, Cho S, Lee JS, Appl. Sci., 10, 1850 (2020)

[15] Raj RP, Ragupathy P, Mohan S, J. Mater. Chem. A, 3, 24338 (2015)

[16] Chen P, Cheng Q, Wang LM, Liu YD, Choi HJ, J. Ind. Eng. Chem., 69, 106 (2019)

[17] Kim M, Kim YK, Kim J, Cho S, Lee G, Jang J, RSC Adv., 6, 27460 (2016)

[18] Park JW, Na W, Jang J, J. Mater. Chem. A, 4, 8263 (2016)

[19] Ramanathan K, Bangar MA, Yun M, Chen W, Myung NV, Mulchandani A, J. Am. Chem. Soc., 127(2), 496 (2005)

[20] Lota K, Khomenko V, Frackowiak E, J. Phys. Chem. Solids, 65, 295 (2004)

[21] Tang HJ, Wang JY, Yin HJ, Zhao HJ, Wang D, Tang ZY, Adv. Mater., 27(6), 1117 (2015)

[22] Sajedi-Moghaddam A, Saievar-Iranizad E, Pumera M, Nanoscale, 9, 8052 (2017)

[23] Kou L, Chen C, Smith SC, J. Phys. Chem. Lett., 6, 2794 (2015)

[24] Extance P, Elliott SR, Philos. Mag. B, 43, 469 (2006)

[25] Guo ZN, Zhang H, Lu SB, Wang ZT, Tang SY, Shao JD, Sun ZB, Xie HH, Wang HY, Yu XF, Chu PK, Adv. Funct. Mater., 25(45), 6996 (2015)

[26] Ribeiro HB, Pimenta MA, de Matos CJS, J. Raman Spectrosc., 49, 76 (2018)

[27] Brent JR, Savjani N, Lewis EA, Haigh SJ, Lewis DJ, O’Brien P, Chem. Commun., 50, 13338 (2014)

[28] Shao L, Sun H, Miao L, Chen X, Han M, Sun J, Liu S, Li L, Cheng F, Chen J, J. Mater. Chem. A, 6, 2494 (2018)

[29] Tabaciarova J, Micusik M, Fedorko P, Omastova M, Polym. Degrad. Stabil., 120, 392 (2015)

[30] Hou Y, Zhang L, Chen LY, Liu P, Hirata A, Chen MW, Phys. Chem. Chem. Phys., 16, 3523 (2014)

[31] Jorio A, Ferreira EHM, Moutinho MVO, Stavale F, Achete CA, Capaz RB, Phys. Status Solidi B, 247, 2980 (2010)

[32] Lucchese MM, Stavale F, Ferreira EHM, Vilani C, Moutinho MVO, Capaz RB, Achete CA, Jorio A, Carbon, 48, 1592 (2010)

[33] Sajedi-Moghaddam A, Mayorga-Martinez CC, Sofer Z, Bousa D, Saievar-Iranizad E, Pumera M, J. Phys. Chem. C, 121, 20532 (2017)

[34] Huang J, Electrochim. Acta, 281, 170 (2018)