화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.34, No.4, 1214-1221, April, 2017
DOI10.1007/s11814-016-0354-5  Export Citation
Pyrolysis kinetic analysis of poly(methyl methacrylate) using evolved gas analysis-mass spectrometry
Tae Uk Han1, Young-Min Kim1, 2, Atsushi Watanabe2, Norio Teramae2, 3, Young-Kwon Park4, and Seungdo Kim1, †
  • 1Department of Environmental Sciences and Biotechnology, Hallym University, Chuncheon 24252, Korea
  • 2Frontier Laboratories Ltd., 4-16-20, Saikon, Koriyama, Fukushima 963-8862, Japan
  • 3Department of Chemistry, Graduate School of Science, Tohoku University, Aoba-ku, Sendai 980-8578, Japan
  • 4School of Environmental Engineering, University of Seoul, Seoul 02504, Korea
E-mail:
The results of evolved gas analysis-mass spectrometry (EGA-MS) analysis were used for the kinetic analysis of poly-methyl methacrylate (PMMA) pyrolysis for the first time. Various kinetic methods, such as model-free, integral master-plots, and model-fitting methods, have been applied to derive the kinetic parameters (activation energy, pre-exponential factor and reaction model). The PMMA pyrolysis reaction mechanism was suggested to occur via a single step unzipping reaction producing methyl methacrylate (MMA) as the main pyrolyzate from the kinetic analysis results and mass spectrum obtained from the EGA-MS measurements. The kinetic parameters derived from modelfree method combined with the integral master-plots method were comparable to those obtained from the peak property method (PPM). The theoretical curve derived from the kinetic results by the PPM was also well matched with the experimental thermal conversion curve using the EGA-MS measurements.
Keywords:PMMA;EGA-MS;Kinetic Analysis;Reaction Model;Py-GC/MS
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