화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.54, 447-453, October, 2017
DOI10.1016/j.jiec.2017.06.026  Export Citation
In-situ catalytic pyrolysis of lignin in a bench-scale fixed bed pyrolyzer
Hoda Shafaghata,1, Pouya Sirous Rezaei1, Donghoon Ro1, Jungho Jae2, 3, Beom-Sik Kim1, Sang-Chul Jung4, Bong Hyun Sung5, and Young-Kwon Park1, †
  • 1School of Environmental Engineering, University of Seoul, Seoul 02504, Republic of Korea
  • 2Clean Energy Research Center, Korea Institute of Science and Technology, Seoul 02792, Republic of Korea
  • 3Department of Clean Energy and Chemical Engineering, Korea University of Science and Technology, Daejeon 34113, Republic of Korea
  • 4Department of Environmental Engineering, Sunchon National University, Suncheon 57922, Republic of Korea
  • 5Bioenergy & Biochemical Research Center, Korea Research Institute of Bioscience & Biotechnology, Daejeon 34141, Republic of Korea
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Thermal and in-situ catalytic pyrolysis of lignin were carried out in a bench-scale pyrolyzer. The yield and composition of the bio-oil produced were influenced largely by the type of lignin samples, pyrolysis temperature, and nitrogen carrier gas flow rate. The highest bio-oil yield of 35.95 wt.% was achieved using kraft lignin at 500 °C and a carrier gas flow rate of 600 ml/min. In-situ catalytic pyrolysis resulted in a decrease of the bio-oil yield, but the aromatic product distribution was altered greatly depending on the types of catalysts. In-situ catalytic pyrolysis also showed enhanced selectivity to valuable aromatic hydrocarbons.
Keywords:In-situ catalytic pyrolysis;Lignin;Bio-oil;Aromatic hydrocarbons;Phenolics
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